The kinetics of the reactions of methyl radicals with Br 2 , Cl 2 , and BrCl
A general competitive method is described for the study of the kinetics of the reactions of radicals with halogens and interhalogen compounds in the gas phase. The method is applied to the reactions equation image over the temperature range of 48°–199°C. It is found that where Θ=2.303RT J/mol. Also...
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| Veröffentlicht in: | International journal of chemical kinetics 1978-07, Vol.10 (7), p.745-757 |
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| container_title | International journal of chemical kinetics |
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| creator | Evans, Brian S. Whittle, Eric |
| description | A general competitive method is described for the study of the kinetics of the reactions of radicals with halogens and interhalogen compounds in the gas phase. The method is applied to the reactions
equation image
over the temperature range of 48°–199°C. It is found that
where Θ=2.303RT J/mol. Also
There is no correlation between differences in activation energies and differences in enthalpy changes for these reactions, but polar effects may be important in reactions (7) and (8). |
| doi_str_mv | 10.1002/kin.550100708 |
| format | Article |
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equation image
over the temperature range of 48°–199°C. It is found that
where Θ=2.303RT J/mol. Also
There is no correlation between differences in activation energies and differences in enthalpy changes for these reactions, but polar effects may be important in reactions (7) and (8).</description><identifier>ISSN: 0538-8066</identifier><identifier>EISSN: 1097-4601</identifier><identifier>DOI: 10.1002/kin.550100708</identifier><language>eng</language><ispartof>International journal of chemical kinetics, 1978-07, Vol.10 (7), p.745-757</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c167t-2647e250d75d81f8347579c5f7421f4ac2a2a215e00cfcdf02c1f7e2d65ddefc3</citedby><cites>FETCH-LOGICAL-c167t-2647e250d75d81f8347579c5f7421f4ac2a2a215e00cfcdf02c1f7e2d65ddefc3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Evans, Brian S.</creatorcontrib><creatorcontrib>Whittle, Eric</creatorcontrib><title>The kinetics of the reactions of methyl radicals with Br 2 , Cl 2 , and BrCl</title><title>International journal of chemical kinetics</title><description>A general competitive method is described for the study of the kinetics of the reactions of radicals with halogens and interhalogen compounds in the gas phase. The method is applied to the reactions
equation image
over the temperature range of 48°–199°C. It is found that
where Θ=2.303RT J/mol. Also
There is no correlation between differences in activation energies and differences in enthalpy changes for these reactions, but polar effects may be important in reactions (7) and (8).</description><issn>0538-8066</issn><issn>1097-4601</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1978</creationdate><recordtype>article</recordtype><recordid>eNo9UE1LxDAUDKJgXT16zw8w63tpk7RHLX5Bwct6LiEfNNptJQnI_nvjKvIO897wZmCGkGuELQLw24-wbIWAsitoT0iF0CnWSMBTUoGoW9aClOfkIqV3AOg6FBUZdpOjRehyMImunuZyR6dNDutyJPYuT4eZRm2D0XOiXyFP9D5STm9oPx9BL7Yw_XxJznx5cVd_uCFvjw-7_pkNr08v_d3ADEqVGZeNclyAVcK26Nu6UUJ1RnjVcPSNNlyXQeEAjDfWAzfoi8JKYa3zpt4Q9utr4ppSdH78jGGv42FEGH-qGEui8b-K-hsuC0-b</recordid><startdate>197807</startdate><enddate>197807</enddate><creator>Evans, Brian S.</creator><creator>Whittle, Eric</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>197807</creationdate><title>The kinetics of the reactions of methyl radicals with Br 2 , Cl 2 , and BrCl</title><author>Evans, Brian S. ; Whittle, Eric</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c167t-2647e250d75d81f8347579c5f7421f4ac2a2a215e00cfcdf02c1f7e2d65ddefc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1978</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Evans, Brian S.</creatorcontrib><creatorcontrib>Whittle, Eric</creatorcontrib><collection>CrossRef</collection><jtitle>International journal of chemical kinetics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Evans, Brian S.</au><au>Whittle, Eric</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The kinetics of the reactions of methyl radicals with Br 2 , Cl 2 , and BrCl</atitle><jtitle>International journal of chemical kinetics</jtitle><date>1978-07</date><risdate>1978</risdate><volume>10</volume><issue>7</issue><spage>745</spage><epage>757</epage><pages>745-757</pages><issn>0538-8066</issn><eissn>1097-4601</eissn><abstract>A general competitive method is described for the study of the kinetics of the reactions of radicals with halogens and interhalogen compounds in the gas phase. The method is applied to the reactions
equation image
over the temperature range of 48°–199°C. It is found that
where Θ=2.303RT J/mol. Also
There is no correlation between differences in activation energies and differences in enthalpy changes for these reactions, but polar effects may be important in reactions (7) and (8).</abstract><doi>10.1002/kin.550100708</doi><tpages>13</tpages></addata></record> |
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| identifier | ISSN: 0538-8066 |
| ispartof | International journal of chemical kinetics, 1978-07, Vol.10 (7), p.745-757 |
| issn | 0538-8066 1097-4601 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_kin_550100708 |
| source | Wiley Online Library Journals Frontfile Complete |
| title | The kinetics of the reactions of methyl radicals with Br 2 , Cl 2 , and BrCl |
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