Kinetics and mechanism of the reaction of para-chlorophenyl aryl chlorophosphates with anilines in acetonitrile

The kinetics and mechanism of the nucleophilic substitution reactions of p‐chlorophenyl aryl chlorophosphates (2) with anilines are investigated in acetonitrile at 55°C. Relatively large magnitudes of ρX and βX values are indicative of a large degree of bond making in the TS. Smaller magnitudes of ρ...

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Veröffentlicht in:International journal of chemical kinetics 2002, Vol.34 (11), p.632-637
Hauptverfasser: Lee, Hai Whang, Guha, Arun Kanti, Lee, Ikchoon
Format: Artikel
Sprache:eng
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