Impact of oenological antioxidant substances on the formation of 1-hydroxyethyl radical and phenolic composition in SO 2 free red wines

Different natural substances, chitosan, inactive dry yeasts and freeze-dried aqueous extracts from two wine industry by-products (stems and shoots) were used in red winemaking as possible alternatives to SO . The resistance to oxidation of wines was evaluated by electron paramagnetic resonance. The...

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Veröffentlicht in:Journal of the science of food and agriculture 2020-06, Vol.100 (8), p.3401-3407
Hauptverfasser: Marchante, Lourdes, Márquez, Katherine, Contreras, David, Izquierdo-Cañas, Pedro M, García-Romero, Esteban, Díaz-Maroto, María C
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container_end_page 3407
container_issue 8
container_start_page 3401
container_title Journal of the science of food and agriculture
container_volume 100
creator Marchante, Lourdes
Márquez, Katherine
Contreras, David
Izquierdo-Cañas, Pedro M
García-Romero, Esteban
Díaz-Maroto, María C
description Different natural substances, chitosan, inactive dry yeasts and freeze-dried aqueous extracts from two wine industry by-products (stems and shoots) were used in red winemaking as possible alternatives to SO . The resistance to oxidation of wines was evaluated by electron paramagnetic resonance. The phenolic composition of wines was analyzed by high-performance liquid chromatography-diode array detection/electrospray ionization mass spectrometry, antioxidant activity was determined by DPPH (1,1-diphenyl-2-picrylhydrazyl radical) and ABTS [2,2'-azinobis-(3-ethylbenzothiazoline-6-sulfonic acid) radical cation] assays and spectrophotometric measurements of color were compared. The wines elaborated with chitosan and inactive dry yeast presented greater capacity to inhibit the formation of the 1-hydroxyethyl radical compared to the wines elaborated with stem or shoot extracts. The total content of anthocyanins was higher in the wines elaborated with SO ; however, the concentration of flavan-3-ols was higher in the wines with chitosan. In addition, the wines with chitosan and inactive dry yeast presented the highest % polymerization. Wines elaborated with stem extract had a lower concentration of flavonols and stilbenes. Chitosan and inactive dry yeast, which are used as an alternative to SO in winemaking, allow the control of the formation of 1-HER in red wines. Wines with stem and shoot extracts showed a lower resistance to oxidation. © 2020 Society of Chemical Industry.
doi_str_mv 10.1002/jsfa.10374
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The resistance to oxidation of wines was evaluated by electron paramagnetic resonance. The phenolic composition of wines was analyzed by high-performance liquid chromatography-diode array detection/electrospray ionization mass spectrometry, antioxidant activity was determined by DPPH (1,1-diphenyl-2-picrylhydrazyl radical) and ABTS [2,2'-azinobis-(3-ethylbenzothiazoline-6-sulfonic acid) radical cation] assays and spectrophotometric measurements of color were compared. The wines elaborated with chitosan and inactive dry yeast presented greater capacity to inhibit the formation of the 1-hydroxyethyl radical compared to the wines elaborated with stem or shoot extracts. The total content of anthocyanins was higher in the wines elaborated with SO ; however, the concentration of flavan-3-ols was higher in the wines with chitosan. In addition, the wines with chitosan and inactive dry yeast presented the highest % polymerization. Wines elaborated with stem extract had a lower concentration of flavonols and stilbenes. Chitosan and inactive dry yeast, which are used as an alternative to SO in winemaking, allow the control of the formation of 1-HER in red wines. 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The resistance to oxidation of wines was evaluated by electron paramagnetic resonance. The phenolic composition of wines was analyzed by high-performance liquid chromatography-diode array detection/electrospray ionization mass spectrometry, antioxidant activity was determined by DPPH (1,1-diphenyl-2-picrylhydrazyl radical) and ABTS [2,2'-azinobis-(3-ethylbenzothiazoline-6-sulfonic acid) radical cation] assays and spectrophotometric measurements of color were compared. The wines elaborated with chitosan and inactive dry yeast presented greater capacity to inhibit the formation of the 1-hydroxyethyl radical compared to the wines elaborated with stem or shoot extracts. The total content of anthocyanins was higher in the wines elaborated with SO ; however, the concentration of flavan-3-ols was higher in the wines with chitosan. In addition, the wines with chitosan and inactive dry yeast presented the highest % polymerization. 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subjects Antioxidants - analysis
Chromatography, High Pressure Liquid
Ethanol - chemistry
Food Handling
Oxidation-Reduction
Phenols - chemistry
Plant Extracts - analysis
Plant Shoots - chemistry
Plant Stems - chemistry
Spectrometry, Mass, Electrospray Ionization
Vitis - chemistry
Wine - analysis
title Impact of oenological antioxidant substances on the formation of 1-hydroxyethyl radical and phenolic composition in SO 2 free red wines
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