Solvent‐Free Synthesis of Surfactants of High‐Carbon Alkyl Phosphates Used for Cosmetics
The solvent‐free synthesis of surfactants of high‐carbon alkyl phosphate esters (C = 18, 22) using the polyphosphoric acid method was studied in this work. Phosphoric acid (85 wt%) and phosphorus pentoxide were used to prepare a phosphorylation agent. The preparation conditions of octadecyl and doco...
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| Veröffentlicht in: | Journal of surfactants and detergents 2018-11, Vol.21 (6), p.789-795 |
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| container_issue | 6 |
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| container_title | Journal of surfactants and detergents |
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| creator | Xu, Dongmei Liu, Zhanglu Gao, Jun Liu, Xiaowei Yan, Peisong Liu, Di Ma, Xiaolong |
| description | The solvent‐free synthesis of surfactants of high‐carbon alkyl phosphate esters (C = 18, 22) using the polyphosphoric acid method was studied in this work. Phosphoric acid (85 wt%) and phosphorus pentoxide were used to prepare a phosphorylation agent. The preparation conditions of octadecyl and docosyl phosphates were optimized. With the optimized synthesis conditions, the high‐carbon alkyl phosphates were prepared with high yield, and their performances were validated. The results indicate that the high‐carbon alkyl phosphates displayed good emulsifying ability and dispersion performance was compared with the other cosmetic surfactants. |
| doi_str_mv | 10.1002/jsde.12191 |
| format | Article |
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Phosphoric acid (85 wt%) and phosphorus pentoxide were used to prepare a phosphorylation agent. The preparation conditions of octadecyl and docosyl phosphates were optimized. With the optimized synthesis conditions, the high‐carbon alkyl phosphates were prepared with high yield, and their performances were validated. The results indicate that the high‐carbon alkyl phosphates displayed good emulsifying ability and dispersion performance was compared with the other cosmetic surfactants.</description><identifier>ISSN: 1097-3958</identifier><identifier>EISSN: 1558-9293</identifier><identifier>DOI: 10.1002/jsde.12191</identifier><language>eng</language><publisher>Hoboken, USA: John Wiley & Sons, Inc</publisher><subject>Cosmetics ; Docosyl phosphates ; Double indicator method ; Octadecyl phosphates ; Synthesis</subject><ispartof>Journal of surfactants and detergents, 2018-11, Vol.21 (6), p.789-795</ispartof><rights>2018 AOCS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2731-2295b461f2a29a32b767bb0d7fe33cf8ff7b69e79b45de744d511f1076ba15ff3</citedby><cites>FETCH-LOGICAL-c2731-2295b461f2a29a32b767bb0d7fe33cf8ff7b69e79b45de744d511f1076ba15ff3</cites><orcidid>0000-0003-1145-9565</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fjsde.12191$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fjsde.12191$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Xu, Dongmei</creatorcontrib><creatorcontrib>Liu, Zhanglu</creatorcontrib><creatorcontrib>Gao, Jun</creatorcontrib><creatorcontrib>Liu, Xiaowei</creatorcontrib><creatorcontrib>Yan, Peisong</creatorcontrib><creatorcontrib>Liu, Di</creatorcontrib><creatorcontrib>Ma, Xiaolong</creatorcontrib><title>Solvent‐Free Synthesis of Surfactants of High‐Carbon Alkyl Phosphates Used for Cosmetics</title><title>Journal of surfactants and detergents</title><description>The solvent‐free synthesis of surfactants of high‐carbon alkyl phosphate esters (C = 18, 22) using the polyphosphoric acid method was studied in this work. 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The results indicate that the high‐carbon alkyl phosphates displayed good emulsifying ability and dispersion performance was compared with the other cosmetic surfactants.</description><subject>Cosmetics</subject><subject>Docosyl phosphates</subject><subject>Double indicator method</subject><subject>Octadecyl phosphates</subject><subject>Synthesis</subject><issn>1097-3958</issn><issn>1558-9293</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp9kLFOwzAURS0EEqWw8AWekQJ-dhzXYxVaCqoEUuiGFNmJTVLSuLIDKBufwDfyJaQtM9O7Tzr3DgehSyDXQAi9WYfSXAMFCUdoBJxPIkklOx4ykSJikk9O0VkI64GFmPMReslc82Ha7ufre-6NwVnfdpUJdcDO4uzdW1V0qu3276J-rQYuVV67Fk-bt77BT5UL20p1JuBVMCW2zuPUhY3p6iKcoxOrmmAu_u4Yreaz53QRLR_v7tPpMiqoYBBRKrmOE7BUUakY1SIRWpNSWMNYYSfWCp1II6SOeWlEHJccwAIRiVbArWVjdHXYLbwLwRubb329Ub7PgeQ7L_nOS773MsBwgD_rxvT_kPlDdjs7dH4BDMpoaQ</recordid><startdate>201811</startdate><enddate>201811</enddate><creator>Xu, Dongmei</creator><creator>Liu, Zhanglu</creator><creator>Gao, Jun</creator><creator>Liu, Xiaowei</creator><creator>Yan, Peisong</creator><creator>Liu, Di</creator><creator>Ma, Xiaolong</creator><general>John Wiley & Sons, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-1145-9565</orcidid></search><sort><creationdate>201811</creationdate><title>Solvent‐Free Synthesis of Surfactants of High‐Carbon Alkyl Phosphates Used for Cosmetics</title><author>Xu, Dongmei ; Liu, Zhanglu ; Gao, Jun ; Liu, Xiaowei ; Yan, Peisong ; Liu, Di ; Ma, Xiaolong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2731-2295b461f2a29a32b767bb0d7fe33cf8ff7b69e79b45de744d511f1076ba15ff3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Cosmetics</topic><topic>Docosyl phosphates</topic><topic>Double indicator method</topic><topic>Octadecyl phosphates</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xu, Dongmei</creatorcontrib><creatorcontrib>Liu, Zhanglu</creatorcontrib><creatorcontrib>Gao, Jun</creatorcontrib><creatorcontrib>Liu, Xiaowei</creatorcontrib><creatorcontrib>Yan, Peisong</creatorcontrib><creatorcontrib>Liu, Di</creatorcontrib><creatorcontrib>Ma, Xiaolong</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of surfactants and detergents</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xu, Dongmei</au><au>Liu, Zhanglu</au><au>Gao, Jun</au><au>Liu, Xiaowei</au><au>Yan, Peisong</au><au>Liu, Di</au><au>Ma, Xiaolong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Solvent‐Free Synthesis of Surfactants of High‐Carbon Alkyl Phosphates Used for Cosmetics</atitle><jtitle>Journal of surfactants and detergents</jtitle><date>2018-11</date><risdate>2018</risdate><volume>21</volume><issue>6</issue><spage>789</spage><epage>795</epage><pages>789-795</pages><issn>1097-3958</issn><eissn>1558-9293</eissn><abstract>The solvent‐free synthesis of surfactants of high‐carbon alkyl phosphate esters (C = 18, 22) using the polyphosphoric acid method was studied in this work. Phosphoric acid (85 wt%) and phosphorus pentoxide were used to prepare a phosphorylation agent. The preparation conditions of octadecyl and docosyl phosphates were optimized. With the optimized synthesis conditions, the high‐carbon alkyl phosphates were prepared with high yield, and their performances were validated. The results indicate that the high‐carbon alkyl phosphates displayed good emulsifying ability and dispersion performance was compared with the other cosmetic surfactants.</abstract><cop>Hoboken, USA</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/jsde.12191</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0003-1145-9565</orcidid></addata></record> |
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| ispartof | Journal of surfactants and detergents, 2018-11, Vol.21 (6), p.789-795 |
| issn | 1097-3958 1558-9293 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_jsde_12191 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Cosmetics Docosyl phosphates Double indicator method Octadecyl phosphates Synthesis |
| title | Solvent‐Free Synthesis of Surfactants of High‐Carbon Alkyl Phosphates Used for Cosmetics |
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