Misassignment of the strong Raman band near 1000 cm−1 in some substituted benzenes, and the Herzberg versus Wilson convention for numbering the vibrations of benzene

Misassignment of the strong Raman band near 1000 cm−1 in some substituted benzenes, and the Herzberg versus Wilson convention for numbering the vibrations of benzene

Mono, 1,3, 5‐substituted benzenes (and only these) have a very strong, highly poarized Raman band at 1000±10 cm−1. It is often misassigned as the symmetrical ring breathing, whereas in fact it is derived from the benzene trigonal ring deformation v6. In the current literature the vibrations of benze...

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Veröffentlicht in:Journal of Raman spectroscopy 1988-05, Vol.19 (3), p.219-221
1. Verfasser: Miller, Foil A.
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Sprache:eng
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Atomic and molecular physics
Exact sciences and technology
Molecular properties and interactions with photons
Molecular spectra
Physics
Raman and rayleigh spectra (including optical scattering)
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description Mono, 1,3, 5‐substituted benzenes (and only these) have a very strong, highly poarized Raman band at 1000±10 cm−1. It is often misassigned as the symmetrical ring breathing, whereas in fact it is derived from the benzene trigonal ring deformation v6. In the current literature the vibrations of benzene are numbered according to either the Herzberg or the Wilson scheme. A plea is made for using only one convention, and reasons are gigen for choosing Herzberg's.
doi_str_mv 10.1002/jrs.1250190313
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subjects Atomic and molecular physics
Exact sciences and technology
Molecular properties and interactions with photons
Molecular spectra
Physics
Raman and rayleigh spectra (including optical scattering)
title Misassignment of the strong Raman band near 1000 cm−1 in some substituted benzenes, and the Herzberg versus Wilson convention for numbering the vibrations of benzene
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