Time‐resolved resonance Raman study of S 1 cis ‐stilbene and its deuterated isotopomers
We present the picosecond time‐resolved resonance Raman (ps‐TR 3 ) spectra of the first excited singlet state (S 1 ) of cis ‐stilbene ( d 0 ), fully deuterated cis ‐stilbene ( d 12 ) and α,α′‐ d 2 ‐ cis ‐stilbene ( d 2 ) measured in hexane at pump and probe wavelengths 267 and 630 nm, respectively....
Gespeichert in:
| Veröffentlicht in: | Journal of Raman spectroscopy 2003-11, Vol.34 (11), p.886-891 |
|---|---|
| Hauptverfasser: | , , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 891 |
|---|---|
| container_issue | 11 |
| container_start_page | 886 |
| container_title | Journal of Raman spectroscopy |
| container_volume | 34 |
| creator | Kwok, W. M. Ma, C. Phillips, D. Beeby, A. Marder, T. B. Thomas, R. Ll Tschuschke, C. Baranović, G. Matousek, P. Towrie, M. Parker, A. W. |
| description | We present the picosecond time‐resolved resonance Raman (ps‐TR
3
) spectra of the first excited singlet state (S
1
) of
cis
‐stilbene (
d
0
), fully deuterated
cis
‐stilbene (
d
12
) and α,α′‐
d
2
‐
cis
‐stilbene (
d
2
) measured in hexane at pump and probe wavelengths 267 and 630 nm, respectively. The main observation is that in the lower wavenumber region the spectra are dominated by a second‐order overtone progression originating from a 229 cm
−1
fundamental band for the S
1
d
0
cis
‐stilbene. The observed low‐wavenumber modes of the excited
cis
‐stilbene are substantially more resonantly enhanced than the modes around 1600 cm
−1
. Copyright © 2003 John Wiley & Sons, Ltd. |
| doi_str_mv | 10.1002/jrs.1070 |
| format | Article |
| fullrecord | <record><control><sourceid>crossref</sourceid><recordid>TN_cdi_crossref_primary_10_1002_jrs_1070</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1002_jrs_1070</sourcerecordid><originalsourceid>FETCH-LOGICAL-c157t-9f4a240288b8318bc09e2c64d1938707c0e90788cc3c3dad8371eaa00d652b073</originalsourceid><addsrcrecordid>eNotkM1KxDAUhYMoOI6Cj5Clm-pN0zbJUgZ1hAFBx5WLkia3kKE_Q25GmJ2P4DP6JLbo6nyLc87iY-xawK0AyO92kSZQcMIWAozKirIsT9kCpFIZFLo6ZxdEOwAwphIL9rENPf58fUeksftEz2cY7OCQv9reDpzSwR_52PI3LrgLxKcypdA1OCC3g-chEfd4SBhtmvaBxjTuxx4jXbKz1naEV_-5ZO-PD9vVOtu8PD2v7jeZE6VKmWkLmxeQa91oKXTjwGDuqsILI7UC5QANKK2dk05667VUAq0F8FWZN6Dkkt38_bo4EkVs630MvY3HWkA9S6knKfUsRf4CTehW8Q</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Time‐resolved resonance Raman study of S 1 cis ‐stilbene and its deuterated isotopomers</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Kwok, W. M. ; Ma, C. ; Phillips, D. ; Beeby, A. ; Marder, T. B. ; Thomas, R. Ll ; Tschuschke, C. ; Baranović, G. ; Matousek, P. ; Towrie, M. ; Parker, A. W.</creator><creatorcontrib>Kwok, W. M. ; Ma, C. ; Phillips, D. ; Beeby, A. ; Marder, T. B. ; Thomas, R. Ll ; Tschuschke, C. ; Baranović, G. ; Matousek, P. ; Towrie, M. ; Parker, A. W.</creatorcontrib><description>We present the picosecond time‐resolved resonance Raman (ps‐TR
3
) spectra of the first excited singlet state (S
1
) of
cis
‐stilbene (
d
0
), fully deuterated
cis
‐stilbene (
d
12
) and α,α′‐
d
2
‐
cis
‐stilbene (
d
2
) measured in hexane at pump and probe wavelengths 267 and 630 nm, respectively. The main observation is that in the lower wavenumber region the spectra are dominated by a second‐order overtone progression originating from a 229 cm
−1
fundamental band for the S
1
d
0
cis
‐stilbene. The observed low‐wavenumber modes of the excited
cis
‐stilbene are substantially more resonantly enhanced than the modes around 1600 cm
−1
. Copyright © 2003 John Wiley & Sons, Ltd.</description><identifier>ISSN: 0377-0486</identifier><identifier>EISSN: 1097-4555</identifier><identifier>DOI: 10.1002/jrs.1070</identifier><language>eng</language><ispartof>Journal of Raman spectroscopy, 2003-11, Vol.34 (11), p.886-891</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c157t-9f4a240288b8318bc09e2c64d1938707c0e90788cc3c3dad8371eaa00d652b073</citedby><cites>FETCH-LOGICAL-c157t-9f4a240288b8318bc09e2c64d1938707c0e90788cc3c3dad8371eaa00d652b073</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Kwok, W. M.</creatorcontrib><creatorcontrib>Ma, C.</creatorcontrib><creatorcontrib>Phillips, D.</creatorcontrib><creatorcontrib>Beeby, A.</creatorcontrib><creatorcontrib>Marder, T. B.</creatorcontrib><creatorcontrib>Thomas, R. Ll</creatorcontrib><creatorcontrib>Tschuschke, C.</creatorcontrib><creatorcontrib>Baranović, G.</creatorcontrib><creatorcontrib>Matousek, P.</creatorcontrib><creatorcontrib>Towrie, M.</creatorcontrib><creatorcontrib>Parker, A. W.</creatorcontrib><title>Time‐resolved resonance Raman study of S 1 cis ‐stilbene and its deuterated isotopomers</title><title>Journal of Raman spectroscopy</title><description>We present the picosecond time‐resolved resonance Raman (ps‐TR
3
) spectra of the first excited singlet state (S
1
) of
cis
‐stilbene (
d
0
), fully deuterated
cis
‐stilbene (
d
12
) and α,α′‐
d
2
‐
cis
‐stilbene (
d
2
) measured in hexane at pump and probe wavelengths 267 and 630 nm, respectively. The main observation is that in the lower wavenumber region the spectra are dominated by a second‐order overtone progression originating from a 229 cm
−1
fundamental band for the S
1
d
0
cis
‐stilbene. The observed low‐wavenumber modes of the excited
cis
‐stilbene are substantially more resonantly enhanced than the modes around 1600 cm
−1
. Copyright © 2003 John Wiley & Sons, Ltd.</description><issn>0377-0486</issn><issn>1097-4555</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><recordid>eNotkM1KxDAUhYMoOI6Cj5Clm-pN0zbJUgZ1hAFBx5WLkia3kKE_Q25GmJ2P4DP6JLbo6nyLc87iY-xawK0AyO92kSZQcMIWAozKirIsT9kCpFIZFLo6ZxdEOwAwphIL9rENPf58fUeksftEz2cY7OCQv9reDpzSwR_52PI3LrgLxKcypdA1OCC3g-chEfd4SBhtmvaBxjTuxx4jXbKz1naEV_-5ZO-PD9vVOtu8PD2v7jeZE6VKmWkLmxeQa91oKXTjwGDuqsILI7UC5QANKK2dk05667VUAq0F8FWZN6Dkkt38_bo4EkVs630MvY3HWkA9S6knKfUsRf4CTehW8Q</recordid><startdate>200311</startdate><enddate>200311</enddate><creator>Kwok, W. M.</creator><creator>Ma, C.</creator><creator>Phillips, D.</creator><creator>Beeby, A.</creator><creator>Marder, T. B.</creator><creator>Thomas, R. Ll</creator><creator>Tschuschke, C.</creator><creator>Baranović, G.</creator><creator>Matousek, P.</creator><creator>Towrie, M.</creator><creator>Parker, A. W.</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>200311</creationdate><title>Time‐resolved resonance Raman study of S 1 cis ‐stilbene and its deuterated isotopomers</title><author>Kwok, W. M. ; Ma, C. ; Phillips, D. ; Beeby, A. ; Marder, T. B. ; Thomas, R. Ll ; Tschuschke, C. ; Baranović, G. ; Matousek, P. ; Towrie, M. ; Parker, A. W.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c157t-9f4a240288b8318bc09e2c64d1938707c0e90788cc3c3dad8371eaa00d652b073</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2003</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kwok, W. M.</creatorcontrib><creatorcontrib>Ma, C.</creatorcontrib><creatorcontrib>Phillips, D.</creatorcontrib><creatorcontrib>Beeby, A.</creatorcontrib><creatorcontrib>Marder, T. B.</creatorcontrib><creatorcontrib>Thomas, R. Ll</creatorcontrib><creatorcontrib>Tschuschke, C.</creatorcontrib><creatorcontrib>Baranović, G.</creatorcontrib><creatorcontrib>Matousek, P.</creatorcontrib><creatorcontrib>Towrie, M.</creatorcontrib><creatorcontrib>Parker, A. W.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of Raman spectroscopy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kwok, W. M.</au><au>Ma, C.</au><au>Phillips, D.</au><au>Beeby, A.</au><au>Marder, T. B.</au><au>Thomas, R. Ll</au><au>Tschuschke, C.</au><au>Baranović, G.</au><au>Matousek, P.</au><au>Towrie, M.</au><au>Parker, A. W.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Time‐resolved resonance Raman study of S 1 cis ‐stilbene and its deuterated isotopomers</atitle><jtitle>Journal of Raman spectroscopy</jtitle><date>2003-11</date><risdate>2003</risdate><volume>34</volume><issue>11</issue><spage>886</spage><epage>891</epage><pages>886-891</pages><issn>0377-0486</issn><eissn>1097-4555</eissn><abstract>We present the picosecond time‐resolved resonance Raman (ps‐TR
3
) spectra of the first excited singlet state (S
1
) of
cis
‐stilbene (
d
0
), fully deuterated
cis
‐stilbene (
d
12
) and α,α′‐
d
2
‐
cis
‐stilbene (
d
2
) measured in hexane at pump and probe wavelengths 267 and 630 nm, respectively. The main observation is that in the lower wavenumber region the spectra are dominated by a second‐order overtone progression originating from a 229 cm
−1
fundamental band for the S
1
d
0
cis
‐stilbene. The observed low‐wavenumber modes of the excited
cis
‐stilbene are substantially more resonantly enhanced than the modes around 1600 cm
−1
. Copyright © 2003 John Wiley & Sons, Ltd.</abstract><doi>10.1002/jrs.1070</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0377-0486 |
| ispartof | Journal of Raman spectroscopy, 2003-11, Vol.34 (11), p.886-891 |
| issn | 0377-0486 1097-4555 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_jrs_1070 |
| source | Wiley Online Library Journals Frontfile Complete |
| title | Time‐resolved resonance Raman study of S 1 cis ‐stilbene and its deuterated isotopomers |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-07T00%3A35%3A49IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Time%E2%80%90resolved%20resonance%20Raman%20study%20of%20S%201%20cis%20%E2%80%90stilbene%20and%20its%20deuterated%20isotopomers&rft.jtitle=Journal%20of%20Raman%20spectroscopy&rft.au=Kwok,%20W.%20M.&rft.date=2003-11&rft.volume=34&rft.issue=11&rft.spage=886&rft.epage=891&rft.pages=886-891&rft.issn=0377-0486&rft.eissn=1097-4555&rft_id=info:doi/10.1002/jrs.1070&rft_dat=%3Ccrossref%3E10_1002_jrs_1070%3C/crossref%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |