Glycosyl Imidates, 78. An Efficient Synthesis of Galactinol and Isogalacatinol

2:3,4:5‐Di‐O‐cyclohexylidene‐D‐/L‐myo‐inositol (2) could be readily converted into 6‐O‐ and 1‐O‐unprotected L‐ and D‐myo‐inositol derivatives L‐ and D‐4 and L‐ and D‐6, respectively. Their reaction with trichloroacetimidate 7 as galactosyl donor in the presence of tin(II) trifluoromethanesulfonate a...

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Veröffentlicht in:	Liebigs Annalen 1997-05, Vol.1997 (5), p.859-863
Hauptverfasser:	Mayer, Thomas G., Schmidt, Richard R.
Format:	Artikel
Sprache:	eng
Schlagworte:	Glycosylation Glycosylation, trichloroacetimidate method myo-Inositol myo‐Inositol, racemate resolution Oligosaccharide racemate resolution Tin(II) trifluoromethanesulfonate catalyst trichloroacetimidate method
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