Flexible, Long-Chain Alkanediamines as Building Blocks for Catenanes - Steric Hindrance of Circumrotation by Derivatization

New catenanes of the amide‐linked type, such as 11 with one macrocycle containing two (CH2)12 chains are synthesized from long‐chain alkanediamines in yields of up to 21%. Consequently, the preorganization afforded by fixed and angular building units – so far considered essential – proves not to be...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Liebigs Annalen 1997-04, Vol.1997 (4), p.761-766
Hauptverfasser:	Baumann, Sven, Jäger, Ralf, Ahuis, Friedrich, Kray, Bernd, Vögtle, Fritz
Format:	Artikel
Sprache:	eng
Schlagworte:	Catenanes Circumrotation Host-guest chemistry Macrocycles Mechanical bonds Template syntheses
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!