Reaction of Benzoyl(thioacetanilides) with α,β-Unsaturated Nitriles; Synthesis of Functionalyzed Pyridines and Thiazoles
The synthesis of spirofused 2‐thioxopyridines 3 from benzoyl(thioacetanilides) 1 and cyclohexylidenemalononitrile (2) is described. Cyclopentylidene‐ and cycloheptylidenemalononitrile do not react with 1. Heating of 1 in the presence of piperidine yields thiazoles 4. The structure of 4a has been est...
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| Veröffentlicht in: | Liebigs Annalen der Chemie 1994-06, Vol.1994 (6), p.633-635 |
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| container_end_page | 635 |
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| container_issue | 6 |
| container_start_page | 633 |
| container_title | Liebigs Annalen der Chemie |
| container_volume | 1994 |
| creator | Bogdanowicz-Szwed, Krystyna Ciechanowicz-Rutkowska, Maria Czarny, Agnieszka Filippini, Giuseppe Pilati, Tulio Rys, Barbara |
| description | The synthesis of spirofused 2‐thioxopyridines 3 from benzoyl(thioacetanilides) 1 and cyclohexylidenemalononitrile (2) is described. Cyclopentylidene‐ and cycloheptylidenemalononitrile do not react with 1. Heating of 1 in the presence of piperidine yields thiazoles 4. The structure of 4a has been established by an X‐ray analysis. |
| doi_str_mv | 10.1002/jlac.199419940616 |
| format | Article |
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Cyclopentylidene‐ and cycloheptylidenemalononitrile do not react with 1. Heating of 1 in the presence of piperidine yields thiazoles 4. 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KGaA, Weinheim</rights><rights>1994 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2836-fef4bc8426ddcb6896509df08dec2bac150abf013c4b0a9fc0210a638bddab2f3</citedby><cites>FETCH-LOGICAL-c2836-fef4bc8426ddcb6896509df08dec2bac150abf013c4b0a9fc0210a638bddab2f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fjlac.199419940616$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fjlac.199419940616$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=4160120$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Bogdanowicz-Szwed, Krystyna</creatorcontrib><creatorcontrib>Ciechanowicz-Rutkowska, Maria</creatorcontrib><creatorcontrib>Czarny, Agnieszka</creatorcontrib><creatorcontrib>Filippini, Giuseppe</creatorcontrib><creatorcontrib>Pilati, Tulio</creatorcontrib><creatorcontrib>Rys, Barbara</creatorcontrib><title>Reaction of Benzoyl(thioacetanilides) with α,β-Unsaturated Nitriles; Synthesis of Functionalyzed Pyridines and Thiazoles</title><title>Liebigs Annalen der Chemie</title><addtitle>Liebigs Ann. Chem</addtitle><description>The synthesis of spirofused 2‐thioxopyridines 3 from benzoyl(thioacetanilides) 1 and cyclohexylidenemalononitrile (2) is described. Cyclopentylidene‐ and cycloheptylidenemalononitrile do not react with 1. Heating of 1 in the presence of piperidine yields thiazoles 4. 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Chem</addtitle><date>1994-06-13</date><risdate>1994</risdate><volume>1994</volume><issue>6</issue><spage>633</spage><epage>635</epage><pages>633-635</pages><issn>0170-2041</issn><eissn>1099-0690</eissn><coden>LACHDL</coden><abstract>The synthesis of spirofused 2‐thioxopyridines 3 from benzoyl(thioacetanilides) 1 and cyclohexylidenemalononitrile (2) is described. Cyclopentylidene‐ and cycloheptylidenemalononitrile do not react with 1. Heating of 1 in the presence of piperidine yields thiazoles 4. The structure of 4a has been established by an X‐ray analysis.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/jlac.199419940616</doi><tpages>3</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0170-2041 |
| ispartof | Liebigs Annalen der Chemie, 1994-06, Vol.1994 (6), p.633-635 |
| issn | 0170-2041 1099-0690 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_jlac_199419940616 |
| source | Wiley Online Library - AutoHoldings Journals |
| subjects | Chemistry Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with n hetero atom and also o and/or s, se, te hetero atoms Michael additions Nitriles Nitriles, α,β‐unsaturated Organic chemistry Organic compounds Physics Preparations and properties Pyridines Structure of solids and liquids crystallography Structure of specific crystalline solids Thiazoles β-unsaturated |
| title | Reaction of Benzoyl(thioacetanilides) with α,β-Unsaturated Nitriles; Synthesis of Functionalyzed Pyridines and Thiazoles |
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