Synthesis of dibenzo-16-crown-5 compounds with pendant ester and ether groups
Structurally related dibenzo‐16‐crown‐5 lariat ethers with pendant ester and ether groups are prepared. Structural variations within the series of alkyl lariat ether esters include changes in the O‐alkyl group, attachment site and nature of the lipophilic group, and length of the spacer, which conne...
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Veröffentlicht in: | Journal of heterocyclic chemistry 2004-09, Vol.41 (5), p.659-675 |
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container_title | Journal of heterocyclic chemistry |
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creator | Babb, David A. Bartsch, Richard A. Collier, James J. Desai, Dhimant H. Elshania, Sadik Goo, Mi-Ja Hallman, Johnny L. Heo, Gwi Suk Huang, Xiaowu Huber, Vincent J. Hwang, Hong-Sik Johnson, Russell J. Liu, Yung Pugia, Michael J. Zhao, Qiang |
description | Structurally related dibenzo‐16‐crown‐5 lariat ethers with pendant ester and ether groups are prepared. Structural variations within the series of alkyl lariat ether esters include changes in the O‐alkyl group, attachment site and nature of the lipophilic group, and length of the spacer, which connects the ester group to the polyether framework. Also synthesized are bis(crown ether) diesters with two dibenzo‐16‐crown‐5 or two dicyclohexano‐16‐crown‐5 units and two ester groups connected to each other by a linker of varying length. Synthetic strategies for the preparation of these lariat ethers with pendant ester‐ and ether‐containing side arms are described. |
doi_str_mv | 10.1002/jhet.5570410503 |
format | Article |
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Structural variations within the series of alkyl lariat ether esters include changes in the O‐alkyl group, attachment site and nature of the lipophilic group, and length of the spacer, which connects the ester group to the polyether framework. Also synthesized are bis(crown ether) diesters with two dibenzo‐16‐crown‐5 or two dicyclohexano‐16‐crown‐5 units and two ester groups connected to each other by a linker of varying length. Synthetic strategies for the preparation of these lariat ethers with pendant ester‐ and ether‐containing side arms are described.</description><identifier>ISSN: 0022-152X</identifier><identifier>EISSN: 1943-5193</identifier><identifier>DOI: 10.1002/jhet.5570410503</identifier><language>eng</language><publisher>Hoboken: Wiley-Blackwell</publisher><ispartof>Journal of heterocyclic chemistry, 2004-09, Vol.41 (5), p.659-675</ispartof><rights>Copyright © 2004 Journal of Heterocyclic Chemistry</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3293-fea72e8ae401f216b9fb55813ebed9d6e9d5d0ef732ac26d4b25559f2142d423</citedby><cites>FETCH-LOGICAL-c3293-fea72e8ae401f216b9fb55813ebed9d6e9d5d0ef732ac26d4b25559f2142d423</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fjhet.5570410503$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fjhet.5570410503$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Babb, David A.</creatorcontrib><creatorcontrib>Bartsch, Richard A.</creatorcontrib><creatorcontrib>Collier, James J.</creatorcontrib><creatorcontrib>Desai, Dhimant H.</creatorcontrib><creatorcontrib>Elshania, Sadik</creatorcontrib><creatorcontrib>Goo, Mi-Ja</creatorcontrib><creatorcontrib>Hallman, Johnny L.</creatorcontrib><creatorcontrib>Heo, Gwi Suk</creatorcontrib><creatorcontrib>Huang, Xiaowu</creatorcontrib><creatorcontrib>Huber, Vincent J.</creatorcontrib><creatorcontrib>Hwang, Hong-Sik</creatorcontrib><creatorcontrib>Johnson, Russell J.</creatorcontrib><creatorcontrib>Liu, Yung</creatorcontrib><creatorcontrib>Pugia, Michael J.</creatorcontrib><creatorcontrib>Zhao, Qiang</creatorcontrib><title>Synthesis of dibenzo-16-crown-5 compounds with pendant ester and ether groups</title><title>Journal of heterocyclic chemistry</title><description>Structurally related dibenzo‐16‐crown‐5 lariat ethers with pendant ester and ether groups are prepared. Structural variations within the series of alkyl lariat ether esters include changes in the O‐alkyl group, attachment site and nature of the lipophilic group, and length of the spacer, which connects the ester group to the polyether framework. Also synthesized are bis(crown ether) diesters with two dibenzo‐16‐crown‐5 or two dicyclohexano‐16‐crown‐5 units and two ester groups connected to each other by a linker of varying length. Synthetic strategies for the preparation of these lariat ethers with pendant ester‐ and ether‐containing side arms are described.</description><issn>0022-152X</issn><issn>1943-5193</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNqFkMtOwzAQRS0EEqWwZusfcOtHnNRihao-gPIQVCo7y4nHNKVNIjtVKF9PqiIQK1ajke65mjkIXTLaY5Ty_moJdU_KhEaMSiqOUIepSBDJlDhGnTbBCZP89RSdhbBqVyaSpIPuX3ZFvYSQB1w6bPMUis-SsJhkvmwKInFWbqpyW9iAm7xe4goKa4oaQ6jBY1NYDC3u8Zsvt1U4RyfOrANcfM8umo9H8-GUzB4nN8PrGckEV4I4MAmHgYGIMsdZnCqXSjlgAlKwysagrLQUXCK4yXhso5RLKVUbjbiNuOii_qG2PTIED05XPt8Yv9OM6r0MvZehf2W0xNWBaPI17P6L69vpaP6HJgc6b7_--KGNf9dxIhKpFw8TfccX6plGY_0kvgBys3P2</recordid><startdate>200409</startdate><enddate>200409</enddate><creator>Babb, David A.</creator><creator>Bartsch, Richard A.</creator><creator>Collier, James J.</creator><creator>Desai, Dhimant H.</creator><creator>Elshania, Sadik</creator><creator>Goo, Mi-Ja</creator><creator>Hallman, Johnny L.</creator><creator>Heo, Gwi Suk</creator><creator>Huang, Xiaowu</creator><creator>Huber, Vincent J.</creator><creator>Hwang, Hong-Sik</creator><creator>Johnson, Russell J.</creator><creator>Liu, Yung</creator><creator>Pugia, Michael J.</creator><creator>Zhao, Qiang</creator><general>Wiley-Blackwell</general><general>Wiley‐Blackwell</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>200409</creationdate><title>Synthesis of dibenzo-16-crown-5 compounds with pendant ester and ether groups</title><author>Babb, David A. ; Bartsch, Richard A. ; Collier, James J. ; Desai, Dhimant H. ; Elshania, Sadik ; Goo, Mi-Ja ; Hallman, Johnny L. ; Heo, Gwi Suk ; Huang, Xiaowu ; Huber, Vincent J. ; Hwang, Hong-Sik ; Johnson, Russell J. ; Liu, Yung ; Pugia, Michael J. ; Zhao, Qiang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3293-fea72e8ae401f216b9fb55813ebed9d6e9d5d0ef732ac26d4b25559f2142d423</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Babb, David A.</creatorcontrib><creatorcontrib>Bartsch, Richard A.</creatorcontrib><creatorcontrib>Collier, James J.</creatorcontrib><creatorcontrib>Desai, Dhimant H.</creatorcontrib><creatorcontrib>Elshania, Sadik</creatorcontrib><creatorcontrib>Goo, Mi-Ja</creatorcontrib><creatorcontrib>Hallman, Johnny L.</creatorcontrib><creatorcontrib>Heo, Gwi Suk</creatorcontrib><creatorcontrib>Huang, Xiaowu</creatorcontrib><creatorcontrib>Huber, Vincent J.</creatorcontrib><creatorcontrib>Hwang, Hong-Sik</creatorcontrib><creatorcontrib>Johnson, Russell J.</creatorcontrib><creatorcontrib>Liu, Yung</creatorcontrib><creatorcontrib>Pugia, Michael J.</creatorcontrib><creatorcontrib>Zhao, Qiang</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>Journal of heterocyclic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Babb, David A.</au><au>Bartsch, Richard A.</au><au>Collier, James J.</au><au>Desai, Dhimant H.</au><au>Elshania, Sadik</au><au>Goo, Mi-Ja</au><au>Hallman, Johnny L.</au><au>Heo, Gwi Suk</au><au>Huang, Xiaowu</au><au>Huber, Vincent J.</au><au>Hwang, Hong-Sik</au><au>Johnson, Russell J.</au><au>Liu, Yung</au><au>Pugia, Michael J.</au><au>Zhao, Qiang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of dibenzo-16-crown-5 compounds with pendant ester and ether groups</atitle><jtitle>Journal of heterocyclic chemistry</jtitle><date>2004-09</date><risdate>2004</risdate><volume>41</volume><issue>5</issue><spage>659</spage><epage>675</epage><pages>659-675</pages><issn>0022-152X</issn><eissn>1943-5193</eissn><abstract>Structurally related dibenzo‐16‐crown‐5 lariat ethers with pendant ester and ether groups are prepared. Structural variations within the series of alkyl lariat ether esters include changes in the O‐alkyl group, attachment site and nature of the lipophilic group, and length of the spacer, which connects the ester group to the polyether framework. Also synthesized are bis(crown ether) diesters with two dibenzo‐16‐crown‐5 or two dicyclohexano‐16‐crown‐5 units and two ester groups connected to each other by a linker of varying length. Synthetic strategies for the preparation of these lariat ethers with pendant ester‐ and ether‐containing side arms are described.</abstract><cop>Hoboken</cop><pub>Wiley-Blackwell</pub><doi>10.1002/jhet.5570410503</doi><tpages>17</tpages></addata></record> |
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title | Synthesis of dibenzo-16-crown-5 compounds with pendant ester and ether groups |
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