Transformations of 2‐aryl‐4‐(2‐oxopyrrolidinyl‐1)‐1,2,3,4‐tetrahydroquinolines, cycloadducts of the BiCl 3 ‐catalyzed three‐component Povarov reaction: Oxidation and reduction processes towards new potentially bioactive 2‐arylquinoline derivatives
magnified image Synthesis and spectral characterization of new series of 2‐aryl‐4‐(2‐oxopyrrolidinyl‐1)‐1,2,3,4‐tetrahydroquinolines and their aromatic analogs, 2‐arylquinolines are reported. It was found that substituted tetrahydroquinoline precursors are easily prepared using BiCl 3 ‐catalyzed thr...
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| Veröffentlicht in: | Journal of heterocyclic chemistry 2010-09, Vol.47 (5), p.1148-1152 |
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| container_title | Journal of heterocyclic chemistry |
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| creator | Kouznetsov, Vladimir V. Meléndez Gómez, Carlos M. Bermúdez Jaimes, John H. |
| description | magnified image
Synthesis and spectral characterization of new series of 2‐aryl‐4‐(2‐oxopyrrolidinyl‐1)‐1,2,3,4‐tetrahydroquinolines and their aromatic analogs, 2‐arylquinolines are reported. It was found that substituted tetrahydroquinoline precursors are easily prepared using BiCl
3
‐catalyzed three‐component Povarov reaction between 4‐nitrobenzaldehyde or 2‐naphtylcarboxyaldehyde, anilines and
N
‐vinylpyrrolidin‐2‐one, and could be transformed
via
oxidation and reduction processes into potentially bioactive 2‐arylquinoline derivatives, unsubstituted at the C‐4 position. The all set of (tetrahydro)quinolines were characterized by IR,
1
H and
13
C‐NMR spectroscopy. J. Heterocyclic Chem., (2010). |
| doi_str_mv | 10.1002/jhet.441 |
| format | Article |
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Synthesis and spectral characterization of new series of 2‐aryl‐4‐(2‐oxopyrrolidinyl‐1)‐1,2,3,4‐tetrahydroquinolines and their aromatic analogs, 2‐arylquinolines are reported. It was found that substituted tetrahydroquinoline precursors are easily prepared using BiCl
3
‐catalyzed three‐component Povarov reaction between 4‐nitrobenzaldehyde or 2‐naphtylcarboxyaldehyde, anilines and
N
‐vinylpyrrolidin‐2‐one, and could be transformed
via
oxidation and reduction processes into potentially bioactive 2‐arylquinoline derivatives, unsubstituted at the C‐4 position. The all set of (tetrahydro)quinolines were characterized by IR,
1
H and
13
C‐NMR spectroscopy. J. Heterocyclic Chem., (2010).</description><identifier>ISSN: 0022-152X</identifier><identifier>EISSN: 1943-5193</identifier><identifier>DOI: 10.1002/jhet.441</identifier><language>eng</language><ispartof>Journal of heterocyclic chemistry, 2010-09, Vol.47 (5), p.1148-1152</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c721-d8b1bf10c6165ac7fa3631d3cfd7da14c9ce5d51a97fcc9fc3fb9fbfc53edcff3</citedby><cites>FETCH-LOGICAL-c721-d8b1bf10c6165ac7fa3631d3cfd7da14c9ce5d51a97fcc9fc3fb9fbfc53edcff3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Kouznetsov, Vladimir V.</creatorcontrib><creatorcontrib>Meléndez Gómez, Carlos M.</creatorcontrib><creatorcontrib>Bermúdez Jaimes, John H.</creatorcontrib><title>Transformations of 2‐aryl‐4‐(2‐oxopyrrolidinyl‐1)‐1,2,3,4‐tetrahydroquinolines, cycloadducts of the BiCl 3 ‐catalyzed three‐component Povarov reaction: Oxidation and reduction processes towards new potentially bioactive 2‐arylquinoline derivatives</title><title>Journal of heterocyclic chemistry</title><description>magnified image
Synthesis and spectral characterization of new series of 2‐aryl‐4‐(2‐oxopyrrolidinyl‐1)‐1,2,3,4‐tetrahydroquinolines and their aromatic analogs, 2‐arylquinolines are reported. It was found that substituted tetrahydroquinoline precursors are easily prepared using BiCl
3
‐catalyzed three‐component Povarov reaction between 4‐nitrobenzaldehyde or 2‐naphtylcarboxyaldehyde, anilines and
N
‐vinylpyrrolidin‐2‐one, and could be transformed
via
oxidation and reduction processes into potentially bioactive 2‐arylquinoline derivatives, unsubstituted at the C‐4 position. The all set of (tetrahydro)quinolines were characterized by IR,
1
H and
13
C‐NMR spectroscopy. J. Heterocyclic Chem., (2010).</description><issn>0022-152X</issn><issn>1943-5193</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNo9UcuO1DAQDAgkhgGJT_BxkSZLHCcTwg1GvKSVlsMcuEWddlvjVcYdbO_shhOfwDfyJdgD2oPdqqp2qawqileyupRVVb-5OVC8bBr5uFjJvlFlK3v1pFglqS5lW39_VjwP4SZBqbpu9Wi99-CCYX-EaNkFwUbUf379Br9MaTTpXGTM9zwv3vNktXVnSb7O16beqE3eihQ9HBbt-cetdWnPUdgIXHBi0PoW49k6Hkh8sLtJKJHeIESYlp-kE--JMsPHmR25KL7xCTyfhCfAnOyduL63-hxSgNOJz6YZzZ6RQqAgIt-B10E4uhMzx2RjYZoWMVrOJid6-NpDRqHJ2xNkMbwonhqYAr38P9fF_tPH_e5LeXX9-evu_VWJXS1L_XaUo5EVbuW2BewMqK2SWqHRnQbZYI_U6lZC3xnE3qAyY29Gg60ijcaodXHxzxY9h-DJDLO3x5RqkNWQOxxyh0PqUP0FcHai0g</recordid><startdate>201009</startdate><enddate>201009</enddate><creator>Kouznetsov, Vladimir V.</creator><creator>Meléndez Gómez, Carlos M.</creator><creator>Bermúdez Jaimes, John H.</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>201009</creationdate><title>Transformations of 2‐aryl‐4‐(2‐oxopyrrolidinyl‐1)‐1,2,3,4‐tetrahydroquinolines, cycloadducts of the BiCl 3 ‐catalyzed three‐component Povarov reaction: Oxidation and reduction processes towards new potentially bioactive 2‐arylquinoline derivatives</title><author>Kouznetsov, Vladimir V. ; Meléndez Gómez, Carlos M. ; Bermúdez Jaimes, John H.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c721-d8b1bf10c6165ac7fa3631d3cfd7da14c9ce5d51a97fcc9fc3fb9fbfc53edcff3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kouznetsov, Vladimir V.</creatorcontrib><creatorcontrib>Meléndez Gómez, Carlos M.</creatorcontrib><creatorcontrib>Bermúdez Jaimes, John H.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of heterocyclic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kouznetsov, Vladimir V.</au><au>Meléndez Gómez, Carlos M.</au><au>Bermúdez Jaimes, John H.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Transformations of 2‐aryl‐4‐(2‐oxopyrrolidinyl‐1)‐1,2,3,4‐tetrahydroquinolines, cycloadducts of the BiCl 3 ‐catalyzed three‐component Povarov reaction: Oxidation and reduction processes towards new potentially bioactive 2‐arylquinoline derivatives</atitle><jtitle>Journal of heterocyclic chemistry</jtitle><date>2010-09</date><risdate>2010</risdate><volume>47</volume><issue>5</issue><spage>1148</spage><epage>1152</epage><pages>1148-1152</pages><issn>0022-152X</issn><eissn>1943-5193</eissn><abstract>magnified image
Synthesis and spectral characterization of new series of 2‐aryl‐4‐(2‐oxopyrrolidinyl‐1)‐1,2,3,4‐tetrahydroquinolines and their aromatic analogs, 2‐arylquinolines are reported. It was found that substituted tetrahydroquinoline precursors are easily prepared using BiCl
3
‐catalyzed three‐component Povarov reaction between 4‐nitrobenzaldehyde or 2‐naphtylcarboxyaldehyde, anilines and
N
‐vinylpyrrolidin‐2‐one, and could be transformed
via
oxidation and reduction processes into potentially bioactive 2‐arylquinoline derivatives, unsubstituted at the C‐4 position. The all set of (tetrahydro)quinolines were characterized by IR,
1
H and
13
C‐NMR spectroscopy. J. Heterocyclic Chem., (2010).</abstract><doi>10.1002/jhet.441</doi><tpages>5</tpages></addata></record> |
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| issn | 0022-152X 1943-5193 |
| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| title | Transformations of 2‐aryl‐4‐(2‐oxopyrrolidinyl‐1)‐1,2,3,4‐tetrahydroquinolines, cycloadducts of the BiCl 3 ‐catalyzed three‐component Povarov reaction: Oxidation and reduction processes towards new potentially bioactive 2‐arylquinoline derivatives |
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