Kinetics of the dissolution of uranium dioxide in nitric acid. I

The kinetics of the dissolution of uranium dioxide in nitric acid have been investigated over a range of acid concentration from 0·3 to 37·0 molal. A change in the reduction mechanism for nitric acid is indicated at about 16 molal concentration. A proposed mechanism for the initial rate period of di...

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Veröffentlicht in:J. Appl. Chem. (London), 18: 129-34(May 1968) 18: 129-34(May 1968), 1968-05, Vol.18 (5), p.129-134
Hauptverfasser: Shabbir, Muhammed, Robins, R. G.
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container_title J. Appl. Chem. (London), 18: 129-34(May 1968)
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creator Shabbir, Muhammed
Robins, R. G.
description The kinetics of the dissolution of uranium dioxide in nitric acid have been investigated over a range of acid concentration from 0·3 to 37·0 molal. A change in the reduction mechanism for nitric acid is indicated at about 16 molal concentration. A proposed mechanism for the initial rate period of dissolution is consistent with experimental results and with the known thermodynamics of the system.
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1934-998X
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subjects N20210 -Chemistry-Inorganic, Organic, & Physical Chemistry-Chemical Properties
NITRIC ACID
NITRIC ACID/uranium dioxide dissolution mechanism
REACTION KINETICS
SOLUBILITY
URANIUM DIOXIDE
URANIUM OXIDES UO$sub 2$/dissolution in nitric acid, mechanism of
title Kinetics of the dissolution of uranium dioxide in nitric acid. I
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