Synthesis of Pteroenone and Its Stereoisomers, a Defensive Metabolite of the Abducted Antarctic Pteropod Clione antarctica

Synthesis of Pteroenone and Its Stereoisomers, a Defensive Metabolite of the Abducted Antarctic Pteropod Clione antarctica

Four stereoisomers of (+)‐pteroenone, a defensive metabolite of the abducted Antarctic pteropod Clione antarctica, were synthesized by employing anti‐/syn‐selective aldol reactions as the key step. These compounds displayed no antifeedant activity against a generally benthic Antarctic fish that does...

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Veröffentlicht in:Helvetica chimica acta 2010-10, Vol.93 (10), p.1933-1944
Hauptverfasser: Asao, Hiroki, Nakamura, Yoko, Furuya, Yukito, Kuwahara, Shigefumi, Baker, Bill J., Kiyota, Hiromasa
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Sprache:eng
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Aldol reaction
Clione antarctica
Marine natural products
Metabolites
Pteroenone
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container_end_page 1944
container_issue 10
container_start_page 1933
container_title Helvetica chimica acta
container_volume 93
creator Asao, Hiroki
Nakamura, Yoko
Furuya, Yukito
Kuwahara, Shigefumi
Baker, Bill J.
Kiyota, Hiromasa
description Four stereoisomers of (+)‐pteroenone, a defensive metabolite of the abducted Antarctic pteropod Clione antarctica, were synthesized by employing anti‐/syn‐selective aldol reactions as the key step. These compounds displayed no antifeedant activity against a generally benthic Antarctic fish that does not co‐occur with this pteropod.
doi_str_mv 10.1002/hlca.201000258
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source Wiley Online Library Journals Frontfile Complete
subjects Aldol reaction
Clione antarctica
Marine natural products
Metabolites
Pteroenone
title Synthesis of Pteroenone and Its Stereoisomers, a Defensive Metabolite of the Abducted Antarctic Pteropod Clione antarctica
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