Rhodium Fluoroapatite Catalyzed Conjugate Addition of Arylboronic Acids to α,β-Unsaturated Carbonyl Compounds

Rhodium fluoroapatite (RhFAP) is an efficient catalyst for conjugate addition of organoboron reagents to α,β‐unsaturated carbonyl compounds. A variety of arylboronic acids and α,β‐unsaturated carbonyl compounds were converted to the corresponding conjugate‐addition products, demonstrating the versat...

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Veröffentlicht in:	Helvetica chimica acta 2008-10, Vol.91 (10), p.1947-1953
Hauptverfasser:	Kantam, Mannepalli Lakshmi, Subrahmanyam, Vura Bala, Shiva Kumar, Kota Balaji, Venkanna, Gopaladasu T., Sreedhar, Bojja
Format:	Artikel
Sprache:	eng
Schlagworte:	5-diene aryl Boronic acid Boronic acid, aryl Carbonyl compounds Carbonyl compounds, α,β‐unsaturated Catalysis Conjugate addition Cycloocta-1 Cycloocta‐1,5‐diene Rhodium catalysis Rhodium fluoroapatite β-unsaturated
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container_end_page	1953
container_issue	10
container_start_page	1947
container_title	Helvetica chimica acta
container_volume	91
creator	Kantam, Mannepalli Lakshmi Subrahmanyam, Vura Bala Shiva Kumar, Kota Balaji Venkanna, Gopaladasu T. Sreedhar, Bojja
description	Rhodium fluoroapatite (RhFAP) is an efficient catalyst for conjugate addition of organoboron reagents to α,β‐unsaturated carbonyl compounds. A variety of arylboronic acids and α,β‐unsaturated carbonyl compounds were converted to the corresponding conjugate‐addition products, demonstrating the versatility of the reaction. The reaction is highly selective. RhFAP was recovered quantitatively by simple filtration, and reused for four cycles.
doi_str_mv	10.1002/hlca.200890208
format	Article
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source	Wiley Online Library Journals Frontfile Complete
subjects	5-diene aryl Boronic acid Boronic acid, aryl Carbonyl compounds Carbonyl compounds, α,β‐unsaturated Catalysis Conjugate addition Cycloocta-1 Cycloocta‐1,5‐diene Rhodium catalysis Rhodium fluoroapatite β-unsaturated
title	Rhodium Fluoroapatite Catalyzed Conjugate Addition of Arylboronic Acids to α,β-Unsaturated Carbonyl Compounds
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