The Relationship of Cycloaddition Reactions to Spontaneous Vinyl Polymerizations

The zwitterionic–biradical tetramethylene proposed by Huisgen as the key intermediate in stepwise [2+2] cycloaddition reactions has been shown to be the crucial intermediate in spontaneous vinyl polymerizations as well. Predominantly biradical tetramethylenes initiate free‐radical copolymerizations,...

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Veröffentlicht in:	Helvetica chimica acta 2005-06, Vol.88 (6), p.1553-1559
Hauptverfasser:	Hall Jr, Henry K., Buyle Padias, Anne
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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