Synthetic studies directed toward the pseurotins. Part II. Synthesis of related highly functionalized furan-3(2H)-ones
The synthesis of 2,2‐bis(hydroxymethyl)‐4‐methyl‐5‐phenylfuran‐3(2H)‐one (9), 5‐[(1S,2S,Z)‐1,2‐(ethylidenedioxy)hex‐3‐enyl]‐2,2‐bis(hydroxymethyl)‐4‐methylfuran‐3(2H)‐one (24), and 5‐[(1S,2S,Z)‐1,2‐(ethylidenedioxy)hex‐3‐enyl]‐2‐(hydroxymethyl)‐4‐methylfuran‐3(2H)‐one (28), which represent more adva...
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| Veröffentlicht in: | Helvetica chimica acta 1990-03, Vol.73 (2), p.483-491 |
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| container_title | Helvetica chimica acta |
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| creator | Dolder, Xie Shao Matthys Tamm, Christoph |
| description | The synthesis of 2,2‐bis(hydroxymethyl)‐4‐methyl‐5‐phenylfuran‐3(2H)‐one (9), 5‐[(1S,2S,Z)‐1,2‐(ethylidenedioxy)hex‐3‐enyl]‐2,2‐bis(hydroxymethyl)‐4‐methylfuran‐3(2H)‐one (24), and 5‐[(1S,2S,Z)‐1,2‐(ethylidenedioxy)hex‐3‐enyl]‐2‐(hydroxymethyl)‐4‐methylfuran‐3(2H)‐one (28), which represent more advanced, suitably functionalized intermediates for the synthesis of pseurotin A (1), a secondary metabolite of Pseudeurotium ovalis STOLK, is described. |
| doi_str_mv | 10.1002/hlca.19900730229 |
| format | Article |
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| source | Wiley Online Library Journals Frontfile Complete |
| title | Synthetic studies directed toward the pseurotins. Part II. Synthesis of related highly functionalized furan-3(2H)-ones |
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