Thermal and Photochemical Reactions of 1,2-Annelated Barrelenes and Hydrobarrelenes in the presence of transition-metal carbonyls

The [Co2(CO)8]‐mediated retro‐Diels‐Alder reaction of the annelated barrelenes 1 afforded the 1H‐indol‐2(3H)‐one derivatives 3 (Scheme 1), while the hydrobarrelene 4a, under the same conditions, was converted to the anilide 6 (Scheme 2); 4b remained unaffected. The direct irradiation of 1 led to the...

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Veröffentlicht in:	Helvetica chimica acta 1989-06, Vol.72 (4), p.648-652
Hauptverfasser:	Trifonov, Latchezar S., Orahovats, Alexander S.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with only one n hetero atom and condensed derivatives Organic chemistry Preparations and properties
Online-Zugang:	Volltext
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