Skeletal Migrations Observed during the Cob(I)alamin-Catalyzed Reduction of 4β-(tert-Butyl)-1β-(1-methylvinyl)cyclohexanecarbaldehyde

Skeletal Migrations Observed during the Cob(I)alamin-Catalyzed Reduction of 4β-(tert-Butyl)-1β-(1-methylvinyl)cyclohexanecarbaldehyde

During the cob(I)alamin(1(I))‐catalyzed reduction of 3, intermediate formation of 2 and final generation of 4–10 was observed (see Scheme 1, cf. Tables 1 and 2). Identical products in similar ratios were generated starting from either 2 or 3. Accepting the intermediate formation of six interconnecte...

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Veröffentlicht in:Helvetica chimica acta 1985-02, Vol.68 (1), p.181-184
Hauptverfasser: Ziegler Jr, Carl B., Fischli, Albert
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Alicyclic compounds
Alicyclic compounds, terpenoids, prostaglandins, steroids
Chemistry
Exact sciences and technology
Organic chemistry
Preparations and properties
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Fischli, Albert
description During the cob(I)alamin(1(I))‐catalyzed reduction of 3, intermediate formation of 2 and final generation of 4–10 was observed (see Scheme 1, cf. Tables 1 and 2). Identical products in similar ratios were generated starting from either 2 or 3. Accepting the intermediate formation of six interconnected cobalt complexes, i.e. A–F (cf. Scheme 2), the generation of all the products observed can be explained.
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subjects Alicyclic compounds
Alicyclic compounds, terpenoids, prostaglandins, steroids
Chemistry
Exact sciences and technology
Organic chemistry
Preparations and properties
title Skeletal Migrations Observed during the Cob(I)alamin-Catalyzed Reduction of 4β-(tert-Butyl)-1β-(1-methylvinyl)cyclohexanecarbaldehyde
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