Beiträge zur Kenntnis des chromophoren Systems der Corrine: XII [1]. Chemische Eigenschaften des Reaktionsproduktes aus Dicyanocobyrinsäure‐heptamethylester mit hypochloriger Säure

Beiträge zur Kenntnis des chromophoren Systems der Corrine: XII [1]. Chemische Eigenschaften des Reaktionsproduktes aus Dicyanocobyrinsäure‐heptamethylester mit hypochloriger Säure

Contributions to the Knowledge of the Corrin Chromophore: XII [1]. Chemical Behaviour of the Reaction Product of Heptamethyl Dicyano‐cobyrinate with Hypochlorous Acid Heptamethyl chloro‐cyano‐5α, 10, 15‐trichloro‐6α, 14‐dihydroxy‐5,6,14,15‐tetrahydrocobyrinate (2) in CH3OH/H2SO4 yields with RuO2 und...

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Veröffentlicht in:Helvetica chimica acta 1981-11, Vol.64 (7), p.2257-2263
Hauptverfasser: Sauer, Ernst Michael, Broschinski, Klaus, Ernst, Ludger, Inhoffen, Hans Herloff
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container_issue 7
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container_title Helvetica chimica acta
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creator Sauer, Ernst Michael
Broschinski, Klaus
Ernst, Ludger
Inhoffen, Hans Herloff
description Contributions to the Knowledge of the Corrin Chromophore: XII [1]. Chemical Behaviour of the Reaction Product of Heptamethyl Dicyano‐cobyrinate with Hypochlorous Acid Heptamethyl chloro‐cyano‐5α, 10, 15‐trichloro‐6α, 14‐dihydroxy‐5,6,14,15‐tetrahydrocobyrinate (2) in CH3OH/H2SO4 yields with RuO2 under 50 bar hydrogen and at 100° during 2 h a mixture of heptamethyl dicyanocobyrinate (1) with an epimeric ester. Using deuterium instead of hydrogen in this reaction, C(13) comes out as the probable epimerization center.
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title Beiträge zur Kenntnis des chromophoren Systems der Corrine: XII [1]. Chemische Eigenschaften des Reaktionsproduktes aus Dicyanocobyrinsäure‐heptamethylester mit hypochloriger Säure
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