Valence Ionization Energies of Hydrocarbons

Experimental valence ionisation energies of 143 hydrocarbons, CnHm, have been determined from their He (IIα) (40.80 eV) and He (Iα) (21.22 eV) excited photoelectron spectra. Ionization energies, usually up to 26 eV are given in tabular form for 108 hydrocarbons with n≤6, together with their (tentati...

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Veröffentlicht in:Helvetica chimica acta 1977-11, Vol.60 (7), p.2213-2233
Hauptverfasser: Bieri, Gerhard, Burger, Fritz, Heilbronner, Edgar, Maier, John P.
Format: Artikel
Sprache:eng
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Zusammenfassung:Experimental valence ionisation energies of 143 hydrocarbons, CnHm, have been determined from their He (IIα) (40.80 eV) and He (Iα) (21.22 eV) excited photoelectron spectra. Ionization energies, usually up to 26 eV are given in tabular form for 108 hydrocarbons with n≤6, together with their (tentative) assignment. The ionization energies up to approximately 25 eV, of 35 selected hydrocarbons with 7≤n≤10, are presented by means of their He (IIα) photoelectron spectra.
ISSN:0018-019X
1522-2675
DOI:10.1002/hlca.19770600714