Niederdruck‐Oligomerisation von Mono‐Olefinen mit löslichen Nickel/Aluminium‐Bimetallkatalysatoren, Teil II Reaktionskinetische Untersuchungen über die Dimerisation von Propen

Niederdruck‐Oligomerisation von Mono‐Olefinen mit löslichen Nickel/Aluminium‐Bimetallkatalysatoren, Teil II Reaktionskinetische Untersuchungen über die Dimerisation von Propen

The kinetics of the dimerization of propene in organic solvents under the influence of a homogeneous catalyst containing π‐tetramethylcyclobutadiene‐nickel dichloride and a prereacted mixture of ethylaluminiumdichloride and tri‐n‐butylphosphin are reported. The primary reaction products are: 2‐methy...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Helvetica chimica acta 1969, Vol.52 (1), p.196-214
Hauptverfasser: Onsager, Olav‐Torgeir, Wang, Hagbarth, Blindheim, Ulf
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 214
container_issue 1
container_start_page 196
container_title Helvetica chimica acta
container_volume 52
creator Onsager, Olav‐Torgeir
Wang, Hagbarth
Blindheim, Ulf
description The kinetics of the dimerization of propene in organic solvents under the influence of a homogeneous catalyst containing π‐tetramethylcyclobutadiene‐nickel dichloride and a prereacted mixture of ethylaluminiumdichloride and tri‐n‐butylphosphin are reported. The primary reaction products are: 2‐methyl‐1‐pentene, 4‐methyl‐2‐pentene (cis/trans), 2,3‐dimethyl‐1‐butene and 2‐Hexene (cis/trans) The results are in accordance with a coordinative mechanism on nickel. New results on the reaction between ethylaluminiumdichloride and O, N and P containing electrondonors are also discussed.
doi_str_mv 10.1002/hlca.19690520120
format Article
fullrecord <record><control><sourceid>wiley_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1002_hlca_19690520120</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>HLCA19690520120</sourcerecordid><originalsourceid>FETCH-LOGICAL-c1420-7f797f677c9a903b9468586f8a426f2a1244fc1172a7be2089a53cd8113c4dec3</originalsourceid><addsrcrecordid>eNqFkMFu1DAQhi1EJZaWO0c_AGnH3iSODxyWpdCVti1CrcQt8jqT7hDHqewEtDcegaeBC7e-CU9SL-VQceEwMxrN_38a_Yy9FHAsAOTJ1llzLHSpoZAgJDxhM1FImclSFU_ZDEBUGQj96Rl7HuNnANAa1Iz9vCBsMDRhst3vb98vHd0MPQaKZqTB8y-pzgc__DlhSx4972nk7u5HdGS3ab0g26E7WbipJ09Tn6RvqMfRONeZ1HcJNQT0r_gVkuOrFf-IptvTY5d4I8WE4dd-xBAnu538TYLe_dpg4A0hf0v_vPMhDLfoj9hBa1zEF3_nIbt-d3q1PMvWl-9Xy8U6syKXkKlWadWWSlltNMw3Oi-roirbyuSybKURMs9bK4SSRm1QQqVNMbdNJcTc5g3a-SGDB64NQ4wB2_o2UG_CrhZQ74Ov98HXj4JPltcPlq_kcPdffX22Xi4e--8Ble6SrQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Niederdruck‐Oligomerisation von Mono‐Olefinen mit löslichen Nickel/Aluminium‐Bimetallkatalysatoren, Teil II Reaktionskinetische Untersuchungen über die Dimerisation von Propen</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Onsager, Olav‐Torgeir ; Wang, Hagbarth ; Blindheim, Ulf</creator><creatorcontrib>Onsager, Olav‐Torgeir ; Wang, Hagbarth ; Blindheim, Ulf</creatorcontrib><description>The kinetics of the dimerization of propene in organic solvents under the influence of a homogeneous catalyst containing π‐tetramethylcyclobutadiene‐nickel dichloride and a prereacted mixture of ethylaluminiumdichloride and tri‐n‐butylphosphin are reported. The primary reaction products are: 2‐methyl‐1‐pentene, 4‐methyl‐2‐pentene (cis/trans), 2,3‐dimethyl‐1‐butene and 2‐Hexene (cis/trans) The results are in accordance with a coordinative mechanism on nickel. New results on the reaction between ethylaluminiumdichloride and O, N and P containing electrondonors are also discussed.</description><identifier>ISSN: 0018-019X</identifier><identifier>EISSN: 1522-2675</identifier><identifier>DOI: 10.1002/hlca.19690520120</identifier><language>eng</language><publisher>Weinheim: WILEY‐VCH Verlag GmbH</publisher><ispartof>Helvetica chimica acta, 1969, Vol.52 (1), p.196-214</ispartof><rights>Copyright © 1969 Verlag GmbH &amp; Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1420-7f797f677c9a903b9468586f8a426f2a1244fc1172a7be2089a53cd8113c4dec3</citedby><cites>FETCH-LOGICAL-c1420-7f797f677c9a903b9468586f8a426f2a1244fc1172a7be2089a53cd8113c4dec3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fhlca.19690520120$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fhlca.19690520120$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1416,4014,27914,27915,27916,45565,45566</link.rule.ids></links><search><creatorcontrib>Onsager, Olav‐Torgeir</creatorcontrib><creatorcontrib>Wang, Hagbarth</creatorcontrib><creatorcontrib>Blindheim, Ulf</creatorcontrib><title>Niederdruck‐Oligomerisation von Mono‐Olefinen mit löslichen Nickel/Aluminium‐Bimetallkatalysatoren, Teil II Reaktionskinetische Untersuchungen über die Dimerisation von Propen</title><title>Helvetica chimica acta</title><description>The kinetics of the dimerization of propene in organic solvents under the influence of a homogeneous catalyst containing π‐tetramethylcyclobutadiene‐nickel dichloride and a prereacted mixture of ethylaluminiumdichloride and tri‐n‐butylphosphin are reported. The primary reaction products are: 2‐methyl‐1‐pentene, 4‐methyl‐2‐pentene (cis/trans), 2,3‐dimethyl‐1‐butene and 2‐Hexene (cis/trans) The results are in accordance with a coordinative mechanism on nickel. New results on the reaction between ethylaluminiumdichloride and O, N and P containing electrondonors are also discussed.</description><issn>0018-019X</issn><issn>1522-2675</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1969</creationdate><recordtype>article</recordtype><recordid>eNqFkMFu1DAQhi1EJZaWO0c_AGnH3iSODxyWpdCVti1CrcQt8jqT7hDHqewEtDcegaeBC7e-CU9SL-VQceEwMxrN_38a_Yy9FHAsAOTJ1llzLHSpoZAgJDxhM1FImclSFU_ZDEBUGQj96Rl7HuNnANAa1Iz9vCBsMDRhst3vb98vHd0MPQaKZqTB8y-pzgc__DlhSx4972nk7u5HdGS3ab0g26E7WbipJ09Tn6RvqMfRONeZ1HcJNQT0r_gVkuOrFf-IptvTY5d4I8WE4dd-xBAnu538TYLe_dpg4A0hf0v_vPMhDLfoj9hBa1zEF3_nIbt-d3q1PMvWl-9Xy8U6syKXkKlWadWWSlltNMw3Oi-roirbyuSybKURMs9bK4SSRm1QQqVNMbdNJcTc5g3a-SGDB64NQ4wB2_o2UG_CrhZQ74Ov98HXj4JPltcPlq_kcPdffX22Xi4e--8Ble6SrQ</recordid><startdate>1969</startdate><enddate>1969</enddate><creator>Onsager, Olav‐Torgeir</creator><creator>Wang, Hagbarth</creator><creator>Blindheim, Ulf</creator><general>WILEY‐VCH Verlag GmbH</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>1969</creationdate><title>Niederdruck‐Oligomerisation von Mono‐Olefinen mit löslichen Nickel/Aluminium‐Bimetallkatalysatoren, Teil II Reaktionskinetische Untersuchungen über die Dimerisation von Propen</title><author>Onsager, Olav‐Torgeir ; Wang, Hagbarth ; Blindheim, Ulf</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1420-7f797f677c9a903b9468586f8a426f2a1244fc1172a7be2089a53cd8113c4dec3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1969</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Onsager, Olav‐Torgeir</creatorcontrib><creatorcontrib>Wang, Hagbarth</creatorcontrib><creatorcontrib>Blindheim, Ulf</creatorcontrib><collection>CrossRef</collection><jtitle>Helvetica chimica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Onsager, Olav‐Torgeir</au><au>Wang, Hagbarth</au><au>Blindheim, Ulf</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Niederdruck‐Oligomerisation von Mono‐Olefinen mit löslichen Nickel/Aluminium‐Bimetallkatalysatoren, Teil II Reaktionskinetische Untersuchungen über die Dimerisation von Propen</atitle><jtitle>Helvetica chimica acta</jtitle><date>1969</date><risdate>1969</risdate><volume>52</volume><issue>1</issue><spage>196</spage><epage>214</epage><pages>196-214</pages><issn>0018-019X</issn><eissn>1522-2675</eissn><abstract>The kinetics of the dimerization of propene in organic solvents under the influence of a homogeneous catalyst containing π‐tetramethylcyclobutadiene‐nickel dichloride and a prereacted mixture of ethylaluminiumdichloride and tri‐n‐butylphosphin are reported. The primary reaction products are: 2‐methyl‐1‐pentene, 4‐methyl‐2‐pentene (cis/trans), 2,3‐dimethyl‐1‐butene and 2‐Hexene (cis/trans) The results are in accordance with a coordinative mechanism on nickel. New results on the reaction between ethylaluminiumdichloride and O, N and P containing electrondonors are also discussed.</abstract><cop>Weinheim</cop><pub>WILEY‐VCH Verlag GmbH</pub><doi>10.1002/hlca.19690520120</doi><tpages>19</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0018-019X
ispartof Helvetica chimica acta, 1969, Vol.52 (1), p.196-214
issn 0018-019X
1522-2675
language eng
recordid cdi_crossref_primary_10_1002_hlca_19690520120
source Wiley Online Library Journals Frontfile Complete
title Niederdruck‐Oligomerisation von Mono‐Olefinen mit löslichen Nickel/Aluminium‐Bimetallkatalysatoren, Teil II Reaktionskinetische Untersuchungen über die Dimerisation von Propen
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-15T06%3A04%3A08IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-wiley_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Niederdruck%E2%80%90Oligomerisation%20von%20Mono%E2%80%90Olefinen%20mit%20l%C3%B6slichen%20Nickel/Aluminium%E2%80%90Bimetallkatalysatoren,%20Teil%20II%20Reaktionskinetische%20Untersuchungen%20%C3%BCber%20die%20Dimerisation%20von%20Propen&rft.jtitle=Helvetica%20chimica%20acta&rft.au=Onsager,%20Olav%E2%80%90Torgeir&rft.date=1969&rft.volume=52&rft.issue=1&rft.spage=196&rft.epage=214&rft.pages=196-214&rft.issn=0018-019X&rft.eissn=1522-2675&rft_id=info:doi/10.1002/hlca.19690520120&rft_dat=%3Cwiley_cross%3EHLCA19690520120%3C/wiley_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true