Abhängigkeit des kinetischen Isotopeneffektes der Azokupplung von Basenkonzentration und Diazokomponente. Zur Kenntnis der Kupplungsreaktion, 10. Mitteilung
1. The kinetic hydrogen isotope effects of azo coupling reactions vary in dependence on three factors, namely the numerical values of k2, k−1 and [B] in the general kinetic equation for electrophilic aromatic substitutions: \documentclass{article}\pagestyle{empty}\begin{document}$$ - \frac{{{\rm d}[...
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| Veröffentlicht in: | Helvetica chimica acta 1955, Vol.38 (6), p.1617-1622 |
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| container_title | Helvetica chimica acta |
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| creator | Zollinger, Hch |
| description | 1. The kinetic hydrogen isotope effects of azo coupling reactions vary in dependence on three factors, namely the numerical values of k2, k−1 and [B] in the general kinetic equation for electrophilic aromatic substitutions:
\documentclass{article}\pagestyle{empty}\begin{document}$$ - \frac{{{\rm d}[{\rm Ar} - {\rm H}]}}{{{\rm dt}}} = [{\rm Ar - H][X]}\frac{{{\rm k}_{\rm 1} \frac{{{\rm k}_2 }}{{{\rm k}_{ - 1} }}[{\rm B}]}}{{{\rm 1 + }\frac{{{\rm k}_{\rm 2} }}{{{\rm k}_{{\rm - 1}} }}[{\rm B}]}} $$\end{document}
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| doi_str_mv | 10.1002/hlca.19550380638 |
| format | Article |
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\documentclass{article}\pagestyle{empty}\begin{document}$$ - \frac{{{\rm d}[{\rm Ar} - {\rm H}]}}{{{\rm dt}}} = [{\rm Ar - H][X]}\frac{{{\rm k}_{\rm 1} \frac{{{\rm k}_2 }}{{{\rm k}_{ - 1} }}[{\rm B}]}}{{{\rm 1 + }\frac{{{\rm k}_{\rm 2} }}{{{\rm k}_{{\rm - 1}} }}[{\rm B}]}} $$\end{document}
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\documentclass{article}\pagestyle{empty}\begin{document}$$ - \frac{{{\rm d}[{\rm Ar} - {\rm H}]}}{{{\rm dt}}} = [{\rm Ar - H][X]}\frac{{{\rm k}_{\rm 1} \frac{{{\rm k}_2 }}{{{\rm k}_{ - 1} }}[{\rm B}]}}{{{\rm 1 + }\frac{{{\rm k}_{\rm 2} }}{{{\rm k}_{{\rm - 1}} }}[{\rm B}]}} $$\end{document}
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\documentclass{article}\pagestyle{empty}\begin{document}$$ - \frac{{{\rm d}[{\rm Ar} - {\rm H}]}}{{{\rm dt}}} = [{\rm Ar - H][X]}\frac{{{\rm k}_{\rm 1} \frac{{{\rm k}_2 }}{{{\rm k}_{ - 1} }}[{\rm B}]}}{{{\rm 1 + }\frac{{{\rm k}_{\rm 2} }}{{{\rm k}_{{\rm - 1}} }}[{\rm B}]}} $$\end{document}
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| ispartof | Helvetica chimica acta, 1955, Vol.38 (6), p.1617-1622 |
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| source | Wiley Online Library Journals Frontfile Complete |
| title | Abhängigkeit des kinetischen Isotopeneffektes der Azokupplung von Basenkonzentration und Diazokomponente. Zur Kenntnis der Kupplungsreaktion, 10. Mitteilung |
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