Aminomethylphosphines in template synthesis on Pt(II), Pd(II), and Hg(II)

Aminomethylphosphines in template synthesis on Pt(II), Pd(II), and Hg(II)

Reactions of 5‐p‐toluidinomethyl‐1,3‐ditolyl‐1,3,5‐diazaphosphorinane 1 with Pt(II), Pd(II), Hg(II) salts are reported. Complex formation was followed by template synthesis of novel bicyclic ligand and chelate complexes. Compounds 2, 3, 4 have been formed. The mercury complex 4 was also obtained in...

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Veröffentlicht in:Heteroatom chemistry 1992-08, Vol.3 (4), p.439-442
Hauptverfasser: Nikonov, G. N., Karasik, A. A., Malova, E. V., Enikeev, K. M.
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container_issue 4
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container_title Heteroatom chemistry
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creator Nikonov, G. N.
Karasik, A. A.
Malova, E. V.
Enikeev, K. M.
description Reactions of 5‐p‐toluidinomethyl‐1,3‐ditolyl‐1,3,5‐diazaphosphorinane 1 with Pt(II), Pd(II), Hg(II) salts are reported. Complex formation was followed by template synthesis of novel bicyclic ligand and chelate complexes. Compounds 2, 3, 4 have been formed. The mercury complex 4 was also obtained in high yield by electrochemical oxidation of compound 1 at the Hg‐anode. Conformational features of new ligands are discussed on the basis of NMR data.
doi_str_mv 10.1002/hc.520030420
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title Aminomethylphosphines in template synthesis on Pt(II), Pd(II), and Hg(II)
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