1-acetoxyvinyl phosphonates: Facile synthesis via catalytic acylation of dialkyl phosphites

A new and facile method of synthesis of 1‐acetoxyvinyl phosphonates (2) has been found. Dialkyl phosphites react readily with acetic anhydride in acetonitrile solution in the presence of catalysts to produce 2 and acylphosphonates (1) as a minor product. The most efficient catalysts are metal compou...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Heteroatom chemistry 1992-04, Vol.3 (2), p.127-131
Hauptverfasser:	Tyryshkin, Nikolay I., Fuzshenokova, Alexandra V., Vedernikov, Andrey N., Solomonov, Boris N.
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!