Electrochemically switchable supramolecular complex between bisporphyrin cleft and electron-deficient aromatic guest
The host–guest complexation between bisporphyrin cleft 1 and flat aromatic guest 2 was controlled by an electrochemical reaction. The first oxidation potentials of 1 showed the anodic shift upon the addition of 2. On the basis of the square scheme, the association constant of 1 with 2 was estimated...
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Veröffentlicht in: | Heteroatom chemistry 2011, Vol.22 (3-4), p.590-593 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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