Thiosilanes in sulfur chemistry: A general approach to silyl thiaheterocycles and their use in stereoselective synthesis

2‐Silyl five‐membered sulfurated heterocycles can be efficiently accessed through reaction of bromo(methoxy)methyl trimethylsilane with suitable β‐substituted mercaptans HS‐CH2CH2‐XH, leading to the formation of 2‐silyl‐1,3‐dithiols, 2‐silyl‐1,3‐thiazolidines, and 2‐silyl‐1,3‐oxathiolanes. β‐Mercapt...

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Veröffentlicht in:	Heteroatom Chemistry 2007-07, Vol.18 (5), p.516-526
Hauptverfasser:	Capperucci, Antonella, Degl'Innocenti, Alessandro, Pollicino, Salvatore, Acciai, Miriam, Castagnoli, Giulio, Malesci, Irene, Tiberi, Caterina
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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