Original recyclization of S-phenacyl derivatives of 4-acylamino-2-mercapto-1,3-oxazoles and their analogues

Original recyclization of S-phenacyl derivatives of 4-acylamino-2-mercapto-1,3-oxazoles and their analogues

Readily accessible acylamino(chloro)acetophenones, if treated with sodium rhodanide and α‐halogenocarbonyl compounds, provide 4‐acylamino‐5‐aryl‐2‐mercapto‐1,3‐oxazole derivatives which undergo recyclization on heating in polyphosphoric acid to give substituted 1,3‐thiazol‐2(3H)‐ones or 1,3‐thiazoli...

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Veröffentlicht in:Heteroatom chemistry 2007-05, Vol.18 (4), p.432-437
Hauptverfasser: Balia, Andrei G., Belyuga, Aleksandr G., Brovarets, Vladimir S., Vasylenko, Aleksandr N., Turov, Aleksandr V., Gakh, Andrei A., Drach, Boris S.
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container_end_page 437
container_issue 4
container_start_page 432
container_title Heteroatom chemistry
container_volume 18
creator Balia, Andrei G.
Belyuga, Aleksandr G.
Brovarets, Vladimir S.
Vasylenko, Aleksandr N.
Turov, Aleksandr V.
Gakh, Andrei A.
Drach, Boris S.
description Readily accessible acylamino(chloro)acetophenones, if treated with sodium rhodanide and α‐halogenocarbonyl compounds, provide 4‐acylamino‐5‐aryl‐2‐mercapto‐1,3‐oxazole derivatives which undergo recyclization on heating in polyphosphoric acid to give substituted 1,3‐thiazol‐2(3H)‐ones or 1,3‐thiazolidin‐2,4‐diones containing 2‐alkyl(aryl)‐5‐aryl‐1,3‐oxazol‐4‐yl residues at the N3 atom. © 2007 Wiley Periodicals, Inc. Heteroatom Chem 18:432–437, 2007; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20317
doi_str_mv 10.1002/hc.20317
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title Original recyclization of S-phenacyl derivatives of 4-acylamino-2-mercapto-1,3-oxazoles and their analogues
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