The semiempirical study on the addition of the chiral ammonium hypophosphite to an aldehyde
The PM3 and AM1 semiempirical computations were performed in order to explain the stereochemistry of the addition of the chiral α‐methylbenzylammonium hypophosphite to an aldehyde, which is stereoselective to 100%. Both mechanisms: one considering the intermediate formation of α‐hydroxy phosphonous...
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| Veröffentlicht in: | Heteroatom chemistry 2004, Vol.15 (2), p.162-168 |
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| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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