A Copper(II) Ion-Selective Potentiometric Sensor Based on N,N′,N″,N′′′-Tetrakis(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane in PVC Matrix
The simple PVC‐based membrane containing N,N′,N″,N′′′‐tetrakis(2‐pyridylmethyl)‐1,4,8,11‐tetraazacyclotetradecane (tpmc) as an ionophore and dibutyl phthalate as a plasticizer, directly coated on a glassy carbon electrode was examined as a new sensor for Cu2+ ions. The potential response was linear...
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| Veröffentlicht in: | Electroanalysis (New York, N.Y.) N.Y.), 2010-08, Vol.22 (16), p.1894-1900 |
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| container_end_page | 1900 |
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| container_issue | 16 |
| container_start_page | 1894 |
| container_title | Electroanalysis (New York, N.Y.) |
| container_volume | 22 |
| creator | Petković, B. B. Sovilj, S. P. Budimir, M. V. Simonović, R. M. Jovanović, V. M. |
| description | The simple PVC‐based membrane containing N,N′,N″,N′′′‐tetrakis(2‐pyridylmethyl)‐1,4,8,11‐tetraazacyclotetradecane (tpmc) as an ionophore and dibutyl phthalate as a plasticizer, directly coated on a glassy carbon electrode was examined as a new sensor for Cu2+ ions. The potential response was linear within the concentration range of 1.0×10−1–1.0×10−6 M with a Nernstian slope of 28.8 mV/decade and detection limit of 7.0×10−7 M. The electrode was used in aqueous solutions over a wide pH range (1.3–6). The sensor exhibited excellent selectivity for Cu2+ ion over a number of cations and was successfully used in its determination in real samples. |
| doi_str_mv | 10.1002/elan.201000053 |
| format | Article |
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The sensor exhibited excellent selectivity for Cu2+ ion over a number of cations and was successfully used in its determination in real samples.</description><identifier>ISSN: 1040-0397</identifier><identifier>EISSN: 1521-4109</identifier><identifier>DOI: 10.1002/elan.201000053</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>11-tetraazacyclotetradecane ; Coated glassy carbon rod ; Cu(II) potentiometric sensors ; Ionophore ; N,N′,N″,N′′′‐Tetrakis(2‐pyridylmethyl)‐1,4,8,11‐tetraazacyclotetradecane ; N′′′-Tetrakis(2-pyridylmethyl)-1 ; Waste waters</subject><ispartof>Electroanalysis (New York, N.Y.), 2010-08, Vol.22 (16), p.1894-1900</ispartof><rights>Copyright © 2010 WILEY‐VCH Verlag GmbH & Co. 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The sensor exhibited excellent selectivity for Cu2+ ion over a number of cations and was successfully used in its determination in real samples.</description><subject>11-tetraazacyclotetradecane</subject><subject>Coated glassy carbon rod</subject><subject>Cu(II) potentiometric sensors</subject><subject>Ionophore</subject><subject>N,N′,N″,N′′′‐Tetrakis(2‐pyridylmethyl)‐1,4,8,11‐tetraazacyclotetradecane</subject><subject>N′′′-Tetrakis(2-pyridylmethyl)-1</subject><subject>Waste waters</subject><issn>1040-0397</issn><issn>1521-4109</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNqFkMtKA0EQRQdR8Ll13UuFdOzn9PQyhqjBGMXnsun0VLB1nAndgzqu_A4_Q__IL3FiRNwJRdUtuKcKbpJsU9KlhLA9KGzZZaTVhEi-lKxRySgWlOjlVhNBMOFarSbrMd61Fp0KvZa89VC_ms0g7AyHu2hYlfgCCnC1fwR0VtVQ1r56gDp4hy6gjFVA-zZCjqoSjTvjz9f3efv4VovCl63b3vu4w_CsCT5vipa_bYpdTDuik3UoxfXcYl-sa1xRfS85OFsC8iU6u-6jE9s-fN5MVqa2iLD1MzeSq4PBZf8Ij04Ph_3eCDuuOccqU1xIqdMJV1Mip_kk15Y4NnGMaG1pZoGTiUhFDkqwVBHGKaVCslyBdC7jG0l3cdeFKsYAUzML_sGGxlBi5smaebLmN9kW0AvgyRfQ_OM2g1Fv_JfFC9bHGp5_WRvuTaq4kuZmfGiYusnSYyHNOf8COgyQDQ</recordid><startdate>201008</startdate><enddate>201008</enddate><creator>Petković, B. 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M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Copper(II) Ion-Selective Potentiometric Sensor Based on N,N′,N″,N′′′-Tetrakis(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane in PVC Matrix</atitle><jtitle>Electroanalysis (New York, N.Y.)</jtitle><addtitle>Electroanalysis</addtitle><date>2010-08</date><risdate>2010</risdate><volume>22</volume><issue>16</issue><spage>1894</spage><epage>1900</epage><pages>1894-1900</pages><issn>1040-0397</issn><eissn>1521-4109</eissn><abstract>The simple PVC‐based membrane containing N,N′,N″,N′′′‐tetrakis(2‐pyridylmethyl)‐1,4,8,11‐tetraazacyclotetradecane (tpmc) as an ionophore and dibutyl phthalate as a plasticizer, directly coated on a glassy carbon electrode was examined as a new sensor for Cu2+ ions. The potential response was linear within the concentration range of 1.0×10−1–1.0×10−6 M with a Nernstian slope of 28.8 mV/decade and detection limit of 7.0×10−7 M. The electrode was used in aqueous solutions over a wide pH range (1.3–6). The sensor exhibited excellent selectivity for Cu2+ ion over a number of cations and was successfully used in its determination in real samples.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/elan.201000053</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1040-0397 |
| ispartof | Electroanalysis (New York, N.Y.), 2010-08, Vol.22 (16), p.1894-1900 |
| issn | 1040-0397 1521-4109 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_elan_201000053 |
| source | Wiley-Blackwell Journals |
| subjects | 11-tetraazacyclotetradecane Coated glassy carbon rod Cu(II) potentiometric sensors Ionophore N,N′,N″,N′′′‐Tetrakis(2‐pyridylmethyl)‐1,4,8,11‐tetraazacyclotetradecane N′′′-Tetrakis(2-pyridylmethyl)-1 Waste waters |
| title | A Copper(II) Ion-Selective Potentiometric Sensor Based on N,N′,N″,N′′′-Tetrakis(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane in PVC Matrix |
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