Determination of Mercury by Chronopotentiometric Stripping Analysis Using Glassy Carbon Vessel as a Working Electrode
In this work chronopotentiometric stripping analysis of mercury was performed using a process vessel of glassy carbon as a working electrode. Experimental parameters for both steady and rotating vessel were investigated and compared. Relative sensitivity as well as the sharpness of the analytical si...
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Veröffentlicht in: | Electroanalysis (New York, N.Y.) N.Y.), 2006-03, Vol.18 (5), p.513-516 |
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creator | Švarc-Gajić, Jaroslava Suturović, Zvonimir Marjanović, Nikola Kravić, Snežana |
description | In this work chronopotentiometric stripping analysis of mercury was performed using a process vessel of glassy carbon as a working electrode. Experimental parameters for both steady and rotating vessel were investigated and compared. Relative sensitivity as well as the sharpness of the analytical signal was better when the rotation of the process vessel was performed. The new design provided better sensitivity when compared to both stationary and rotating glassy carbon disk electrodes. Detection limit obtained for the electrolysis time of 600 s was 0.1 ng/L of Hg(II). The accuracy of the technique was confirmed by analyzing the standard reference material – tomato leaves. |
doi_str_mv | 10.1002/elan.200503410 |
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Experimental parameters for both steady and rotating vessel were investigated and compared. Relative sensitivity as well as the sharpness of the analytical signal was better when the rotation of the process vessel was performed. The new design provided better sensitivity when compared to both stationary and rotating glassy carbon disk electrodes. Detection limit obtained for the electrolysis time of 600 s was 0.1 ng/L of Hg(II). The accuracy of the technique was confirmed by analyzing the standard reference material – tomato leaves.</description><identifier>ISSN: 1040-0397</identifier><identifier>EISSN: 1521-4109</identifier><identifier>DOI: 10.1002/elan.200503410</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Chronopotentiometric stripping analysis ; Glassy carbon vessel working electrode ; Mercury</subject><ispartof>Electroanalysis (New York, N.Y.), 2006-03, Vol.18 (5), p.513-516</ispartof><rights>Copyright © 2006 WILEY‐VCH Verlag GmbH & Co. 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Experimental parameters for both steady and rotating vessel were investigated and compared. Relative sensitivity as well as the sharpness of the analytical signal was better when the rotation of the process vessel was performed. The new design provided better sensitivity when compared to both stationary and rotating glassy carbon disk electrodes. Detection limit obtained for the electrolysis time of 600 s was 0.1 ng/L of Hg(II). The accuracy of the technique was confirmed by analyzing the standard reference material – tomato leaves.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/elan.200503410</doi><tpages>4</tpages></addata></record> |
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subjects | Chronopotentiometric stripping analysis Glassy carbon vessel working electrode Mercury |
title | Determination of Mercury by Chronopotentiometric Stripping Analysis Using Glassy Carbon Vessel as a Working Electrode |
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