[CpRh III ] in an Ionic Liquid as a Highly Efficient and Recyclable Catalytic Medium for Regio‐ and Diastereoselective Csp 3 –H Carbenoid Insertion
Reported herein is a bidentate‐assisted Csp 3 –H bond insertion using Cp*Rh III /IL as a highly efficient and recyclable catalytic medium, while showing good functional group tolerance. Notably, the application of ionic liquid not only lowered the temperature, but also enhanced the diastereoselectiv...
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| Veröffentlicht in: | European journal of organic chemistry 2019-12, Vol.2019 (45), p.7448-7451 |
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| container_end_page | 7451 |
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| container_issue | 45 |
| container_start_page | 7448 |
| container_title | European journal of organic chemistry |
| container_volume | 2019 |
| creator | Li, Jianglian Zhou, Lin Wang, Yaoling Ma, Qiang Lei, Yuan Lai, Ruizhi Luo, Yi Hai, Li Wu, Yong |
| description | Reported herein is a bidentate‐assisted Csp
3
–H bond insertion using Cp*Rh
III
/IL as a highly efficient and recyclable catalytic medium, while showing good functional group tolerance. Notably, the application of ionic liquid not only lowered the temperature, but also enhanced the diastereoselectivity of this reaction. This work significantly expanded the scope of ionic liquids in Csp
3
–H functionalizations. |
| doi_str_mv | 10.1002/ejoc.201901279 |
| format | Article |
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3
–H bond insertion using Cp*Rh
III
/IL as a highly efficient and recyclable catalytic medium, while showing good functional group tolerance. Notably, the application of ionic liquid not only lowered the temperature, but also enhanced the diastereoselectivity of this reaction. This work significantly expanded the scope of ionic liquids in Csp
3
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3
–H bond insertion using Cp*Rh
III
/IL as a highly efficient and recyclable catalytic medium, while showing good functional group tolerance. Notably, the application of ionic liquid not only lowered the temperature, but also enhanced the diastereoselectivity of this reaction. This work significantly expanded the scope of ionic liquids in Csp
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| ispartof | European journal of organic chemistry, 2019-12, Vol.2019 (45), p.7448-7451 |
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| language | eng |
| recordid | cdi_crossref_primary_10_1002_ejoc_201901279 |
| source | Access via Wiley Online Library |
| title | [CpRh III ] in an Ionic Liquid as a Highly Efficient and Recyclable Catalytic Medium for Regio‐ and Diastereoselective Csp 3 –H Carbenoid Insertion |
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