Cascade S N 2′–S N Ar, Elimination, and 1,5‐Hydride Shift Reactions by Acetylacetone/Acetoacetic Esters: Synthesis of 9,10‐Dihydroacridines
A reaction involving the use of acetylacetone/methyl acetoacetate and Morita–Baylis–Hillman acetates for the efficient, one‐pot, metal‐free synthesis of 9,10‐dihydroacridines at room temperature was developed. The cascade of reactions involved sequential S N 2′–S N Ar reactions, elimination, and red...
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| Veröffentlicht in: | European journal of organic chemistry 2016-10, Vol.2016 (29), p.4981-4984 |
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| container_end_page | 4984 |
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| container_issue | 29 |
| container_start_page | 4981 |
| container_title | European journal of organic chemistry |
| container_volume | 2016 |
| creator | Gupta, Tanu Bharadwaj, Kishor Chandra Singh, Radhey M. |
| description | A reaction involving the use of acetylacetone/methyl acetoacetate and Morita–Baylis–Hillman acetates for the efficient, one‐pot, metal‐free synthesis of 9,10‐dihydroacridines at room temperature was developed. The cascade of reactions involved sequential S
N
2′–S
N
Ar reactions, elimination, and reduction through ketene generation and hydride transfer. Evidence for hydride shift via a ketene intermediate was also discussed. |
| doi_str_mv | 10.1002/ejoc.201600911 |
| format | Article |
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N
2′–S
N
Ar reactions, elimination, and reduction through ketene generation and hydride transfer. Evidence for hydride shift via a ketene intermediate was also discussed.</abstract><doi>10.1002/ejoc.201600911</doi><tpages>4</tpages></addata></record> |
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| identifier | ISSN: 1434-193X |
| ispartof | European journal of organic chemistry, 2016-10, Vol.2016 (29), p.4981-4984 |
| issn | 1434-193X 1099-0690 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_ejoc_201600911 |
| source | Wiley Online Library |
| title | Cascade S N 2′–S N Ar, Elimination, and 1,5‐Hydride Shift Reactions by Acetylacetone/Acetoacetic Esters: Synthesis of 9,10‐Dihydroacridines |
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