High Regiocontrol in the Zinc-Mediated Crotylation of Aldehydes and Ketones: A Straightforward and Facile Approach to Linear Homoallylic Alcohols in DMPU

The α‐regioselectivity of carbonyl crotylation is a long‐standing problem in the realm of C–C bond formation reactions. We demonstrate that zinc‐mediated crotylation of aldehydes and ketones can afford α‐linear homoallylic alcohols exclusively to provide a simple solution for this problem. In this c...

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Veröffentlicht in:	European journal of organic chemistry 2012-05, Vol.2012 (13), p.2579-2584
Hauptverfasser:	Zhao, Li-Ming, Wan, Li-Jing, Jin, Hai-Shan, Zhang, Shu-Qing
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes Chemistry Exact sciences and technology Ketones Kinetics and mechanisms Organic chemistry Reaction mechanisms Reactivity and mechanisms Regioselectivity
Online-Zugang:	Volltext
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