Heck-Matsuda Reaction for Allylic Nitro Compounds: A Short Asymmetric Synthesis of an FTY720 Derivative

The Heck–Matsuda reaction for allylic nitro compounds effectively afforded cinnamyl nitro compounds in good yields. Aryldiazonium salts that have an electron‐donating substituent underwent a smooth reaction in the presence of Pd2dba3. A palladium complex that coordinated with an electron‐rich ligand...

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Veröffentlicht in:	European journal of organic chemistry 2012-04, Vol.2012 (11), p.2161-2166
Hauptverfasser:	Nakano, Toshiki, Miyahara, Mizuki, Itoh, Toshiyuki, Kamimura, Akio
Format:	Artikel
Sprache:	eng
Schlagworte:	Allylic compounds C-C coupling Chemistry Exact sciences and technology Nitro compounds Noncondensed benzenic compounds Organic chemistry Palladium Preparations and properties Synthetic methods
Online-Zugang:	Volltext
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