Preparation of Pillar[n]arenes by Cyclooligomerization of 2,5-Dialkoxybenzyl Alcohols or 2,5-Dialkoxybenzyl Bromides
The facile and efficient preparation of pillar[n]arenes (n = 5 or 6) was achieved by cyclooligomerization of 2,5‐dialkoxybenzyl alcohols or 2,5‐dialkoxybenzyl bromides with an appropriate Lewis acid catalyst at room temperature. The mechanism for this cyclooligomerization is presumed to be a Friedel...
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| Veröffentlicht in: | European Journal of Organic Chemistry 2011-09, Vol.2011 (27), p.5331-5335 |
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| container_end_page | 5335 |
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| container_issue | 27 |
| container_start_page | 5331 |
| container_title | European Journal of Organic Chemistry |
| container_volume | 2011 |
| creator | Ma, Yingjie Zhang, Zibin Ji, Xiaofan Han, Chengyou He, Jiuming Abliz, Zeper Chen, Weixiang Huang, Feihe |
| description | The facile and efficient preparation of pillar[n]arenes (n = 5 or 6) was achieved by cyclooligomerization of 2,5‐dialkoxybenzyl alcohols or 2,5‐dialkoxybenzyl bromides with an appropriate Lewis acid catalyst at room temperature. The mechanism for this cyclooligomerization is presumed to be a Friedel–Crafts alkylation.
The facile and efficient preparation of pillar[n]arenes (n = 5 or 6) was achieved by cyclooligomerization of 2,5‐dialkoxybenzyl alcohols or 2,5‐dialkoxybenzyl bromideswith an appropriate Lewis acid catalyst at room temperature. The mechanism for this cyclooligomerization is presumed to be a Friedel–Crafts alkylation. |
| doi_str_mv | 10.1002/ejoc.201100698 |
| format | Article |
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The facile and efficient preparation of pillar[n]arenes (n = 5 or 6) was achieved by cyclooligomerization of 2,5‐dialkoxybenzyl alcohols or 2,5‐dialkoxybenzyl bromideswith an appropriate Lewis acid catalyst at room temperature. The mechanism for this cyclooligomerization is presumed to be a Friedel–Crafts alkylation.</description><identifier>ISSN: 1434-193X</identifier><identifier>EISSN: 1099-0690</identifier><identifier>DOI: 10.1002/ejoc.201100698</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Alicyclic compounds ; Alicyclic compounds, terpenoids, prostaglandins, steroids ; Arenes ; Calixarenes ; Chemistry ; Cross-disciplinary physics: materials science; rheology ; Cyclooligomerization ; Exact sciences and technology ; Host-guest systems ; Macrocycles ; Materials science ; Methods of nanofabrication ; Organic chemistry ; Physics ; Pillar[n]arenes ; Preparations and properties ; Supramolecular and biochemical assembly ; Supramolecular chemistry</subject><ispartof>European Journal of Organic Chemistry, 2011-09, Vol.2011 (27), p.5331-5335</ispartof><rights>Copyright © 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4238-7814db084ea29e7977ff6525f7d8b7d1602b3db7d69b356386fe882751d0517d3</citedby><cites>FETCH-LOGICAL-c4238-7814db084ea29e7977ff6525f7d8b7d1602b3db7d69b356386fe882751d0517d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fejoc.201100698$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fejoc.201100698$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>313,314,776,780,788,1411,27899,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=24519809$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Ma, Yingjie</creatorcontrib><creatorcontrib>Zhang, Zibin</creatorcontrib><creatorcontrib>Ji, Xiaofan</creatorcontrib><creatorcontrib>Han, Chengyou</creatorcontrib><creatorcontrib>He, Jiuming</creatorcontrib><creatorcontrib>Abliz, Zeper</creatorcontrib><creatorcontrib>Chen, Weixiang</creatorcontrib><creatorcontrib>Huang, Feihe</creatorcontrib><title>Preparation of Pillar[n]arenes by Cyclooligomerization of 2,5-Dialkoxybenzyl Alcohols or 2,5-Dialkoxybenzyl Bromides</title><title>European Journal of Organic Chemistry</title><addtitle>Eur. J. Org. Chem</addtitle><description>The facile and efficient preparation of pillar[n]arenes (n = 5 or 6) was achieved by cyclooligomerization of 2,5‐dialkoxybenzyl alcohols or 2,5‐dialkoxybenzyl bromides with an appropriate Lewis acid catalyst at room temperature. The mechanism for this cyclooligomerization is presumed to be a Friedel–Crafts alkylation.
The facile and efficient preparation of pillar[n]arenes (n = 5 or 6) was achieved by cyclooligomerization of 2,5‐dialkoxybenzyl alcohols or 2,5‐dialkoxybenzyl bromideswith an appropriate Lewis acid catalyst at room temperature. The mechanism for this cyclooligomerization is presumed to be a Friedel–Crafts alkylation.</description><subject>Alicyclic compounds</subject><subject>Alicyclic compounds, terpenoids, prostaglandins, steroids</subject><subject>Arenes</subject><subject>Calixarenes</subject><subject>Chemistry</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Cyclooligomerization</subject><subject>Exact sciences and technology</subject><subject>Host-guest systems</subject><subject>Macrocycles</subject><subject>Materials science</subject><subject>Methods of nanofabrication</subject><subject>Organic chemistry</subject><subject>Physics</subject><subject>Pillar[n]arenes</subject><subject>Preparations and properties</subject><subject>Supramolecular and biochemical assembly</subject><subject>Supramolecular chemistry</subject><issn>1434-193X</issn><issn>1099-0690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkEtLw0AUhYMoWKtb19m4M3UeyTyWNdZWKW0XVQsiwySZ6NRppswUbPrrTYkUF4Krey73fOfCCYJLCHoQAHSjljbvIQCbhXB2FHQg4DxqNDhudIzjCHK8OA3OvF8CADghsBNsZk6tpZMbbavQluFMGyPda_UmnaqUD7M6TOvcWGv0u10pp3cHK7pOojstzafd1pmqdrUJ-ya3H9b40Lq_zrfOrnSh_HlwUkrj1cXP7AZP94N5OorG0-FD2h9HeYwwiyiDcZEBFiuJuKKc0rIkCUpKWrCMFpAAlOGiUYRnOCGYkVIxhmgCC5BAWuBu0Gtzc2e9d6oUa6dX0tUCArHvTOw7E4fOGuCqBdbS59KUTla59gcKxQnkDPDGx1vflzaq_idVDB6n6e8fUctqv1HbAyvdpyAU00S8TIYCTsBoMU-ReMbfmhiN4Q</recordid><startdate>201109</startdate><enddate>201109</enddate><creator>Ma, Yingjie</creator><creator>Zhang, Zibin</creator><creator>Ji, Xiaofan</creator><creator>Han, Chengyou</creator><creator>He, Jiuming</creator><creator>Abliz, Zeper</creator><creator>Chen, Weixiang</creator><creator>Huang, Feihe</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley-VCH</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>201109</creationdate><title>Preparation of Pillar[n]arenes by Cyclooligomerization of 2,5-Dialkoxybenzyl Alcohols or 2,5-Dialkoxybenzyl Bromides</title><author>Ma, Yingjie ; Zhang, Zibin ; Ji, Xiaofan ; Han, Chengyou ; He, Jiuming ; Abliz, Zeper ; Chen, Weixiang ; Huang, Feihe</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4238-7814db084ea29e7977ff6525f7d8b7d1602b3db7d69b356386fe882751d0517d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Alicyclic compounds</topic><topic>Alicyclic compounds, terpenoids, prostaglandins, steroids</topic><topic>Arenes</topic><topic>Calixarenes</topic><topic>Chemistry</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Cyclooligomerization</topic><topic>Exact sciences and technology</topic><topic>Host-guest systems</topic><topic>Macrocycles</topic><topic>Materials science</topic><topic>Methods of nanofabrication</topic><topic>Organic chemistry</topic><topic>Physics</topic><topic>Pillar[n]arenes</topic><topic>Preparations and properties</topic><topic>Supramolecular and biochemical assembly</topic><topic>Supramolecular chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ma, Yingjie</creatorcontrib><creatorcontrib>Zhang, Zibin</creatorcontrib><creatorcontrib>Ji, Xiaofan</creatorcontrib><creatorcontrib>Han, Chengyou</creatorcontrib><creatorcontrib>He, Jiuming</creatorcontrib><creatorcontrib>Abliz, Zeper</creatorcontrib><creatorcontrib>Chen, Weixiang</creatorcontrib><creatorcontrib>Huang, Feihe</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>European Journal of Organic Chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ma, Yingjie</au><au>Zhang, Zibin</au><au>Ji, Xiaofan</au><au>Han, Chengyou</au><au>He, Jiuming</au><au>Abliz, Zeper</au><au>Chen, Weixiang</au><au>Huang, Feihe</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation of Pillar[n]arenes by Cyclooligomerization of 2,5-Dialkoxybenzyl Alcohols or 2,5-Dialkoxybenzyl Bromides</atitle><jtitle>European Journal of Organic Chemistry</jtitle><addtitle>Eur. J. Org. Chem</addtitle><date>2011-09</date><risdate>2011</risdate><volume>2011</volume><issue>27</issue><spage>5331</spage><epage>5335</epage><pages>5331-5335</pages><issn>1434-193X</issn><eissn>1099-0690</eissn><abstract>The facile and efficient preparation of pillar[n]arenes (n = 5 or 6) was achieved by cyclooligomerization of 2,5‐dialkoxybenzyl alcohols or 2,5‐dialkoxybenzyl bromides with an appropriate Lewis acid catalyst at room temperature. The mechanism for this cyclooligomerization is presumed to be a Friedel–Crafts alkylation.
The facile and efficient preparation of pillar[n]arenes (n = 5 or 6) was achieved by cyclooligomerization of 2,5‐dialkoxybenzyl alcohols or 2,5‐dialkoxybenzyl bromideswith an appropriate Lewis acid catalyst at room temperature. The mechanism for this cyclooligomerization is presumed to be a Friedel–Crafts alkylation.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/ejoc.201100698</doi><tpages>5</tpages></addata></record> |
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| ispartof | European Journal of Organic Chemistry, 2011-09, Vol.2011 (27), p.5331-5335 |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Alicyclic compounds Alicyclic compounds, terpenoids, prostaglandins, steroids Arenes Calixarenes Chemistry Cross-disciplinary physics: materials science rheology Cyclooligomerization Exact sciences and technology Host-guest systems Macrocycles Materials science Methods of nanofabrication Organic chemistry Physics Pillar[n]arenes Preparations and properties Supramolecular and biochemical assembly Supramolecular chemistry |
| title | Preparation of Pillar[n]arenes by Cyclooligomerization of 2,5-Dialkoxybenzyl Alcohols or 2,5-Dialkoxybenzyl Bromides |
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