Oxidation of Sulfides with a Silica-Supported Peracid in Supercritical Carbon Dioxide under Flow Conditions: Tuning Chemoselectivity with Pressure

Supercritical carbon dioxide is a convenient medium for performing the selective oxidation of sulfides 1 to either sulfoxides 2 or sulfones 3 with [2‐percarboxyethyl]‐functionalized silica (4) under flow conditions. The chemoselectivity of the reaction, which results from the different diffusion rat...

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Veröffentlicht in:	European Journal of Organic Chemistry 2010-11, Vol.2010 (32), p.6200-6206
Hauptverfasser:	Mello, Rossella, Olmos, Andrea, Alcalde-Aragonés, Ana, Díaz-Rodríguez, Alba, González Núñez, María Elena, Asensio, Gregorio
Format:	Artikel
Sprache:	eng
Schlagworte:	Adsorption Catalysis Catalysts: preparations and properties Chemistry Exact sciences and technology General and physical chemistry Noncondensed benzenic compounds Organic chemistry Oxidation Preparations and properties Supercritical CO2 Supported catalysts Surface diffusion Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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