N‐Allylideneamines Derived from Acrolein: Synthesis and Use as Acceptors of Two Nucleophiles

Two practical methods have been developed for the preparation of N‐allylideneamines 1b,c. One involves the isomerization of propargylamines and the other the dehydration of acrolein. N‐Allylideneamines 1b,c thus prepared were used as efficient substrates for 1,4‐ and 1,2‐double nucleophilic addition...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	European Journal of Organic Chemistry 2009-08, Vol.2009 (24), p.4073-4084
Hauptverfasser:	Mizota, Isao, Matsuda, Yuri, Hachiya, Iwao, Shimizu, Makoto
Format:	Artikel
Sprache:	eng
Schlagworte:	Aliphatic compounds Allylic compounds Amines Amino acids Chemistry Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with only one n hetero atom and condensed derivatives Nucleophilic addition Organic chemistry Preparations and properties Regioselectivity
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!