Synthesis of Methanes Having Four Different Carbon Substituents Utilizing Indium‐Catalyzed Cleavage of Carbon–Pyrrolyl Bonds

A pyrrolyl group bound to an sp3 carbon atom in gem‐dipyrrolylalkanes was found to be successfully replaced by a certain range of carbon nucleophiles in the presence of an indium catalyst. The reaction can also be performed efficiently as a three‐component assembly of alkynes, pyrroles, and carbon n...

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Veröffentlicht in:	European journal of organic chemistry 2009-05, Vol.2009 (15), p.2437-2440
Hauptverfasser:	Tsuchimoto, Teruhisa, Ainoya, Taku, Aoki, Kazuki, Wagatsuma, Tatsuya, Shirakawa, Eiji
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkynes Catalysis Catalysts: preparations and properties Chemistry C–C activation Exact sciences and technology General and physical chemistry Heterocycles Heterocyclic compounds Heterocyclic compounds with only one n hetero atom and condensed derivatives Indium Nucleo­philic substitution Organic chemistry Preparations and properties Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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