One-Pot, Selective Hydroformylation, Condensation, and Hydrogenation Processes by a Sol-Gel Entrapped Rhodium Complex, an Immobilized Base, and an Ionic Liquid

We report on a one‐pot, multistep process in which styrene derivatives are selectively hydroformylated to give branched aldehydes, which in turn, are condensed with reactive methylene compounds (malononitrile, ethyl cyanoacetate), and then hydrogenated. The process takes place at 80 °C under 20.7 ba...

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Veröffentlicht in:	European Journal of Organic Chemistry 2009-04, Vol.2009 (10), p.1502-1505
Hauptverfasser:	Hamza, Khalil, Schumann, Herbert, Blum, Jochanan
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Catalysts: preparations and properties Chemistry Exact sciences and technology General and physical chemistry Hydroformylation Hydrogenation Ionic liquids Kinetics and mechanisms Noncondensed benzenic compounds Organic chemistry Preparations and properties Reactivity and mechanisms Rhodium Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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