Stereoselective Functionalization of Dihydropyran‐3‐ols: Application to the Synthesis of Enantiopure Ethyl Deoxymonate B

The behavior of readily available enantiopure cis and trans 3,6‐disubstituted dihydropyran‐3‐ols and derivatives in epoxidation, osmium‐catalyzed dihydroxylations, SN2′, and Claisen‐related processes has been examined. The highly diastereoselective dihydroxylation of a suitably functionalized cis 3,...

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Veröffentlicht in:	European Journal of Organic Chemistry 2009-05, Vol.2009 (14), p.2312-2322
Hauptverfasser:	Fernández de la Pradilla, Roberto, Lwoff, Nadia, Viso, Alma
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Dihydroxylation Epoxidation Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives Metathesis Organic chemistry Oxygen heterocycles Preparations and properties Rearrangement
Online-Zugang:	Volltext
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