1,1′-Bi(trishomobarrelenyl) - Synthesis and Chiroptic Properties

1,1′‐Bi(endo,exo,syn‐pentacyclo[3.3.3.02,4.06,8.09,11]undecyl)[1,1′‐bi(trishomobarrelenyl)] (4) has been prepared as a 1:1 mixture of its meso‐ and d,l‐diastereomers in six steps from trishomobarrelene 1 via the amine 5, the N,N′‐bis(trishomobarrelenyl)sulfamide 6 and the 1,2‐(trishomobarrelenyl)dia...

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Veröffentlicht in:	European Journal of Organic Chemistry 2009-03, Vol.2009 (7), p.1048-1052
Hauptverfasser:	de Meijere, Armin, Rauch, Karsten, Schrader, Bernhard, Brackmann, Farina, Pfoh, Roland, Rühl, Stephan, Katoh, Yasunaka, Okamoto, Yoshio, Wodrich, Matthew D., Corminboeuf, Clémence, Schreiner, Peter R.
Format:	Artikel
Sprache:	eng
Schlagworte:	Alicyclic compounds Alicyclic compounds, terpenoids, prostaglandins, steroids Chemistry Chirality Density functional calculations Exact sciences and technology Helical structures Oligocyclic cyclopropane derivatives Organic chemistry Preparations and properties Small ring systems
Online-Zugang:	Volltext
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