Fluorinated Johnson Reagent for Transfer-Trifluoromethylation to Carbon Nucleophiles
A novel reagent, [(oxido)phenyl(trifluoromethyl)‐λ4‐sulfanylidene]dimethylammonium tetrafluoroborate has been developed for the electrophilic trifluoromethylation of carbon nucleophiles. The reagent was designed as a trifluorinated version of a Johnson‐type methyl‐transfer reagent. The firstexample...
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| Veröffentlicht in: | European Journal of Organic Chemistry 2008-07, Vol.2008 (20), p.3465-3468 |
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| container_end_page | 3468 |
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| container_issue | 20 |
| container_start_page | 3465 |
| container_title | European Journal of Organic Chemistry |
| container_volume | 2008 |
| creator | Noritake, Shun Shibata, Norio Nakamura, Shuichi Toru, Takeshi Shiro, Motoo |
| description | A novel reagent, [(oxido)phenyl(trifluoromethyl)‐λ4‐sulfanylidene]dimethylammonium tetrafluoroborate has been developed for the electrophilic trifluoromethylation of carbon nucleophiles. The reagent was designed as a trifluorinated version of a Johnson‐type methyl‐transfer reagent. The firstexample of vinylogous trifluoromethylation of dicyanoalkylidenes is also demonstrated.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
A novel reagent for the electrophilic trifluoromethylation of carbon nucleophiles is described. The reagent was designed as a trifluorinated version of a Johnson‐type methyl‐transfer reagent. |
| doi_str_mv | 10.1002/ejoc.200800419 |
| format | Article |
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A novel reagent for the electrophilic trifluoromethylation of carbon nucleophiles is described. The reagent was designed as a trifluorinated version of a Johnson‐type methyl‐transfer reagent.</description><identifier>ISSN: 1434-193X</identifier><identifier>EISSN: 1099-0690</identifier><identifier>DOI: 10.1002/ejoc.200800419</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>C-C bond formation ; Electrophilic ; Fluorine ; Sulfur ; Trifluoromethylation</subject><ispartof>European Journal of Organic Chemistry, 2008-07, Vol.2008 (20), p.3465-3468</ispartof><rights>Copyright © 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3939-e00cabb006abbec859e3dd1ec1c6bb1c67c686d767e286cfc9cb72b8da236f723</citedby><cites>FETCH-LOGICAL-c3939-e00cabb006abbec859e3dd1ec1c6bb1c67c686d767e286cfc9cb72b8da236f723</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fejoc.200800419$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fejoc.200800419$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>313,314,776,780,788,1411,27899,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Noritake, Shun</creatorcontrib><creatorcontrib>Shibata, Norio</creatorcontrib><creatorcontrib>Nakamura, Shuichi</creatorcontrib><creatorcontrib>Toru, Takeshi</creatorcontrib><creatorcontrib>Shiro, Motoo</creatorcontrib><title>Fluorinated Johnson Reagent for Transfer-Trifluoromethylation to Carbon Nucleophiles</title><title>European Journal of Organic Chemistry</title><addtitle>Eur. J. Org. Chem</addtitle><description>A novel reagent, [(oxido)phenyl(trifluoromethyl)‐λ4‐sulfanylidene]dimethylammonium tetrafluoroborate has been developed for the electrophilic trifluoromethylation of carbon nucleophiles. The reagent was designed as a trifluorinated version of a Johnson‐type methyl‐transfer reagent. The firstexample of vinylogous trifluoromethylation of dicyanoalkylidenes is also demonstrated.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
A novel reagent for the electrophilic trifluoromethylation of carbon nucleophiles is described. The reagent was designed as a trifluorinated version of a Johnson‐type methyl‐transfer reagent.</description><subject>C-C bond formation</subject><subject>Electrophilic</subject><subject>Fluorine</subject><subject>Sulfur</subject><subject>Trifluoromethylation</subject><issn>1434-193X</issn><issn>1099-0690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNqFkE9PwkAUxDdGExG9eu4XKL7twrZ7NBVQQiBg_XPbbLdvpVi6ZLdE-faWYIg3LzNzmN_LyxByS6FHAaI7XFvdiwASgD4VZ6RDQYgQuIDzNvdZP6SCvV-SK-_XACA4px2SjaqddWWtGiyCiV3V3tbBEtUH1k1grAsyp2pv0IWZK82hazfYrPaVasq22dggVS5v02ynK7TbVVmhvyYXRlUeb369S15Gwyx9DKfz8VN6Pw01E0yECKBVngPwVlEnA4GsKChqqnmetxJrnvAi5jFGCddGC53HUZ4UKmLcxBHrkt7xrnbWe4dGbl25UW4vKcjDJvKwiTxt0gLiCHy1b-7_acvhZJ7-ZcMjW_oGv0-scp-SxyweyLfZWC6fXxeLB5rJBfsBJnx4WA</recordid><startdate>200807</startdate><enddate>200807</enddate><creator>Noritake, Shun</creator><creator>Shibata, Norio</creator><creator>Nakamura, Shuichi</creator><creator>Toru, Takeshi</creator><creator>Shiro, Motoo</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>200807</creationdate><title>Fluorinated Johnson Reagent for Transfer-Trifluoromethylation to Carbon Nucleophiles</title><author>Noritake, Shun ; Shibata, Norio ; Nakamura, Shuichi ; Toru, Takeshi ; Shiro, Motoo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3939-e00cabb006abbec859e3dd1ec1c6bb1c67c686d767e286cfc9cb72b8da236f723</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>C-C bond formation</topic><topic>Electrophilic</topic><topic>Fluorine</topic><topic>Sulfur</topic><topic>Trifluoromethylation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Noritake, Shun</creatorcontrib><creatorcontrib>Shibata, Norio</creatorcontrib><creatorcontrib>Nakamura, Shuichi</creatorcontrib><creatorcontrib>Toru, Takeshi</creatorcontrib><creatorcontrib>Shiro, Motoo</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>European Journal of Organic Chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Noritake, Shun</au><au>Shibata, Norio</au><au>Nakamura, Shuichi</au><au>Toru, Takeshi</au><au>Shiro, Motoo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fluorinated Johnson Reagent for Transfer-Trifluoromethylation to Carbon Nucleophiles</atitle><jtitle>European Journal of Organic Chemistry</jtitle><addtitle>Eur. J. Org. Chem</addtitle><date>2008-07</date><risdate>2008</risdate><volume>2008</volume><issue>20</issue><spage>3465</spage><epage>3468</epage><pages>3465-3468</pages><issn>1434-193X</issn><eissn>1099-0690</eissn><abstract>A novel reagent, [(oxido)phenyl(trifluoromethyl)‐λ4‐sulfanylidene]dimethylammonium tetrafluoroborate has been developed for the electrophilic trifluoromethylation of carbon nucleophiles. The reagent was designed as a trifluorinated version of a Johnson‐type methyl‐transfer reagent. The firstexample of vinylogous trifluoromethylation of dicyanoalkylidenes is also demonstrated.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
A novel reagent for the electrophilic trifluoromethylation of carbon nucleophiles is described. The reagent was designed as a trifluorinated version of a Johnson‐type methyl‐transfer reagent.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/ejoc.200800419</doi><tpages>4</tpages></addata></record> |
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| ispartof | European Journal of Organic Chemistry, 2008-07, Vol.2008 (20), p.3465-3468 |
| issn | 1434-193X 1099-0690 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_ejoc_200800419 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | C-C bond formation Electrophilic Fluorine Sulfur Trifluoromethylation |
| title | Fluorinated Johnson Reagent for Transfer-Trifluoromethylation to Carbon Nucleophiles |
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