Radical Cations in Electrospray Mass Spectrometry: Formation of Open‐Shell Species, Examination of the Fragmentation Behaviour in ESI‐MS n and Reaction Mechanism Studies by Detection of Transient Radical Cations

The ion formation mechanism in electrospray MS is reviewed, with special focus on the electrochemical red/ox reactions responsible for the formation of radical molecular ions. Prerequisites influencing the likelihood of formation and observation of a particular compound as an open‐shell molecular sp...

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Veröffentlicht in:	European journal of organic chemistry 2007-11, Vol.2007 (31), p.5162-5174
Hauptverfasser:	Schäfer, Mathias, Drayß, Miriam, Springer, Andreas, Zacharias, Philipp, Meerholz, Klaus
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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