Enantioselective Synthesis of Thiosulfinates and of Acyclic Alkylidenemethylene Sulfide Sulfoxides

Enantioselectivities up to 75 % have been found in the catalytic mono‐oxidation of di‐tert‐butyl disulfide and related compounds as well as of ketene‐S,S‐acetals with an in situ generated chiral dioxirane. The effect of solvents on the enantiomeric excess has also been examined. (© Wiley‐VCH Verlag...

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Veröffentlicht in:	European Journal of Organic Chemistry 2005-05, Vol.2005 (9), p.1727-1730
Hauptverfasser:	Colonna, Stefano, Pironti, Vincenza, Drabowicz, Jozef, Brebion, Franck, Fensterbank, Louis, Malacria, Max
Format:	Artikel
Sprache:	eng
Schlagworte:	Asymmetric synthesis Bovine serum albumin Chiral dioxirane Enantioselectivity Thiosulfinate
Online-Zugang:	Volltext
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