Synthesis of a Novel Cyclic Chlorophyll Hetero-Dyad as a Model Compound for Stacked Chlorophylls Found in Photosynthetic Systems

Synthesis of a Novel Cyclic Chlorophyll Hetero-Dyad as a Model Compound for Stacked Chlorophylls Found in Photosynthetic Systems

A covalently doubly linked cyclic chlorophyll hetero‐dyad was stereospecifically prepared as a model for naturally stacked chlorophyll suprastructures. In the synthetic dyad, two composite macrocycles are situated very close to each other such that the Qy transition dipole moments intramolecularly i...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:European journal of organic chemistry 2004-06, Vol.2004 (11), p.2325-2330
Hauptverfasser: Kosaka, Nobuo, Tamiaki, Hitoshi
Format: Artikel
Sprache:eng
Schlagworte:
Conformation analysis
Cyclizations
Molecular modeling
Porphyrinoids
Stacking interactions
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 2330
container_issue 11
container_start_page 2325
container_title European journal of organic chemistry
container_volume 2004
creator Kosaka, Nobuo
Tamiaki, Hitoshi
description A covalently doubly linked cyclic chlorophyll hetero‐dyad was stereospecifically prepared as a model for naturally stacked chlorophyll suprastructures. In the synthetic dyad, two composite macrocycles are situated very close to each other such that the Qy transition dipole moments intramolecularly interact to give intense circular dichroism peaks. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)
doi_str_mv 10.1002/ejoc.200400027
format Article
fullrecord <record><control><sourceid>istex_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1002_ejoc_200400027</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>ark_67375_WNG_9HKPXLFW_9</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3257-139b44c6e52f30ae46f0e47d912ec3b22af1acc2e328560b15ad6de86fd319053</originalsourceid><addsrcrecordid>eNqFkEtPAjEUhRujiYhuXfcPDPYx06FLM4KoCCRoYNeUPjIDAyXt-JidP90BDGHn6t6be75zcw8Atxh1MELkziyd6hCEYtRM6RloYcR5hBhH500f0zjCnM4vwVUIy0bCGcMt8DOtN1VuQhGgs1DCkfs0JcxqVRYKZnnpvNvmdVnCgamMd9FDLTWUoVG-Or1TuvXWfWw0tM7DaSXVyuhTLsD-fl1s4CR3lQv7c1VjPq1DZdbhGlxYWQZz81fb4L3fe8sG0XD8-JTdDyNFSZJGmPJFHCtmEmIpkiZmFpk41RwTo-iCEGmxVIoYSroJQwucSM206TKrKeYooW3QOfgq70LwxoqtL9bS1wIjsctP7PITx_wagB-Ar6I09T9q0XseZ6dsdGCL5sfvIyv9SrCUpomYjR4FH7xM5sP-THD6CxKohf0</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Synthesis of a Novel Cyclic Chlorophyll Hetero-Dyad as a Model Compound for Stacked Chlorophylls Found in Photosynthetic Systems</title><source>Wiley Journals</source><creator>Kosaka, Nobuo ; Tamiaki, Hitoshi</creator><creatorcontrib>Kosaka, Nobuo ; Tamiaki, Hitoshi</creatorcontrib><description>A covalently doubly linked cyclic chlorophyll hetero‐dyad was stereospecifically prepared as a model for naturally stacked chlorophyll suprastructures. In the synthetic dyad, two composite macrocycles are situated very close to each other such that the Qy transition dipole moments intramolecularly interact to give intense circular dichroism peaks. (© Wiley‐VCH Verlag GmbH &amp; Co. KGaA, 69451 Weinheim, Germany, 2004)</description><identifier>ISSN: 1434-193X</identifier><identifier>EISSN: 1099-0690</identifier><identifier>DOI: 10.1002/ejoc.200400027</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Conformation analysis ; Cyclizations ; Molecular modeling ; Porphyrinoids ; Stacking interactions</subject><ispartof>European journal of organic chemistry, 2004-06, Vol.2004 (11), p.2325-2330</ispartof><rights>Copyright © 2004 WILEY‐VCH Verlag GmbH &amp; Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3257-139b44c6e52f30ae46f0e47d912ec3b22af1acc2e328560b15ad6de86fd319053</citedby><cites>FETCH-LOGICAL-c3257-139b44c6e52f30ae46f0e47d912ec3b22af1acc2e328560b15ad6de86fd319053</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fejoc.200400027$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fejoc.200400027$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Kosaka, Nobuo</creatorcontrib><creatorcontrib>Tamiaki, Hitoshi</creatorcontrib><title>Synthesis of a Novel Cyclic Chlorophyll Hetero-Dyad as a Model Compound for Stacked Chlorophylls Found in Photosynthetic Systems</title><title>European journal of organic chemistry</title><addtitle>Eur. J. Org. Chem</addtitle><description>A covalently doubly linked cyclic chlorophyll hetero‐dyad was stereospecifically prepared as a model for naturally stacked chlorophyll suprastructures. In the synthetic dyad, two composite macrocycles are situated very close to each other such that the Qy transition dipole moments intramolecularly interact to give intense circular dichroism peaks. (© Wiley‐VCH Verlag GmbH &amp; Co. KGaA, 69451 Weinheim, Germany, 2004)</description><subject>Conformation analysis</subject><subject>Cyclizations</subject><subject>Molecular modeling</subject><subject>Porphyrinoids</subject><subject>Stacking interactions</subject><issn>1434-193X</issn><issn>1099-0690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNqFkEtPAjEUhRujiYhuXfcPDPYx06FLM4KoCCRoYNeUPjIDAyXt-JidP90BDGHn6t6be75zcw8Atxh1MELkziyd6hCEYtRM6RloYcR5hBhH500f0zjCnM4vwVUIy0bCGcMt8DOtN1VuQhGgs1DCkfs0JcxqVRYKZnnpvNvmdVnCgamMd9FDLTWUoVG-Or1TuvXWfWw0tM7DaSXVyuhTLsD-fl1s4CR3lQv7c1VjPq1DZdbhGlxYWQZz81fb4L3fe8sG0XD8-JTdDyNFSZJGmPJFHCtmEmIpkiZmFpk41RwTo-iCEGmxVIoYSroJQwucSM206TKrKeYooW3QOfgq70LwxoqtL9bS1wIjsctP7PITx_wagB-Ar6I09T9q0XseZ6dsdGCL5sfvIyv9SrCUpomYjR4FH7xM5sP-THD6CxKohf0</recordid><startdate>200406</startdate><enddate>200406</enddate><creator>Kosaka, Nobuo</creator><creator>Tamiaki, Hitoshi</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>200406</creationdate><title>Synthesis of a Novel Cyclic Chlorophyll Hetero-Dyad as a Model Compound for Stacked Chlorophylls Found in Photosynthetic Systems</title><author>Kosaka, Nobuo ; Tamiaki, Hitoshi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3257-139b44c6e52f30ae46f0e47d912ec3b22af1acc2e328560b15ad6de86fd319053</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Conformation analysis</topic><topic>Cyclizations</topic><topic>Molecular modeling</topic><topic>Porphyrinoids</topic><topic>Stacking interactions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kosaka, Nobuo</creatorcontrib><creatorcontrib>Tamiaki, Hitoshi</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>European journal of organic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kosaka, Nobuo</au><au>Tamiaki, Hitoshi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of a Novel Cyclic Chlorophyll Hetero-Dyad as a Model Compound for Stacked Chlorophylls Found in Photosynthetic Systems</atitle><jtitle>European journal of organic chemistry</jtitle><addtitle>Eur. J. Org. Chem</addtitle><date>2004-06</date><risdate>2004</risdate><volume>2004</volume><issue>11</issue><spage>2325</spage><epage>2330</epage><pages>2325-2330</pages><issn>1434-193X</issn><eissn>1099-0690</eissn><abstract>A covalently doubly linked cyclic chlorophyll hetero‐dyad was stereospecifically prepared as a model for naturally stacked chlorophyll suprastructures. In the synthetic dyad, two composite macrocycles are situated very close to each other such that the Qy transition dipole moments intramolecularly interact to give intense circular dichroism peaks. (© Wiley‐VCH Verlag GmbH &amp; Co. KGaA, 69451 Weinheim, Germany, 2004)</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/ejoc.200400027</doi><tpages>6</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1434-193X
ispartof European journal of organic chemistry, 2004-06, Vol.2004 (11), p.2325-2330
issn 1434-193X
1099-0690
language eng
recordid cdi_crossref_primary_10_1002_ejoc_200400027
source Wiley Journals
subjects Conformation analysis
Cyclizations
Molecular modeling
Porphyrinoids
Stacking interactions
title Synthesis of a Novel Cyclic Chlorophyll Hetero-Dyad as a Model Compound for Stacked Chlorophylls Found in Photosynthetic Systems
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-05T08%3A59%3A28IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-istex_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20of%20a%20Novel%20Cyclic%20Chlorophyll%20Hetero-Dyad%20as%20a%20Model%20Compound%20for%20Stacked%20Chlorophylls%20Found%20in%20Photosynthetic%20Systems&rft.jtitle=European%20journal%20of%20organic%20chemistry&rft.au=Kosaka,%20Nobuo&rft.date=2004-06&rft.volume=2004&rft.issue=11&rft.spage=2325&rft.epage=2330&rft.pages=2325-2330&rft.issn=1434-193X&rft.eissn=1099-0690&rft_id=info:doi/10.1002/ejoc.200400027&rft_dat=%3Cistex_cross%3Eark_67375_WNG_9HKPXLFW_9%3C/istex_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true