Synthesis and Molecular Modeling Studies of SYNPHOS®, a New, Efficient Diphosphane Ligand For Ruthenium-Catalyzed Asymmetric Hydrogenation

A new, optically active, atropisomeric diphosphane ligand, (2,3,2′,3′‐tetrahydro‐5,5′‐bi(1,4‐benzodioxin)‐6,6′‐diyl)bis‐(diphenylphosphane) (SYNPHOS®), has been synthesized, characterized, and used in ruthenium‐catalyzed asymmetric hydrogenations. This new ligand has been compared with other atropis...

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Veröffentlicht in:	European journal of organic chemistry 2003-05, Vol.2003 (10), p.1931-1941
Hauptverfasser:	Paule, Sébastien Duprat de, Jeulin, Séverine, Ratovelomanana-Vidal, Virginie, Genêt, Jean-Pierre, Champion, Nicolas, Dellis, Philippe
Format:	Artikel
Sprache:	eng
Schlagworte:	Asymmetric catalysis Atropisomerism Hydrogenation Molecular modeling Phosphanes Ruthenium
Online-Zugang:	Volltext
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