Cover Feature: Pressure‐Induced Encapsulation of Cs+ Cations within an 18‐Crown‐6 Cavity: Insights from X‐ray Diffraction, Raman Spectroscopy, and DFT Calculations (Eur. J. Inorg. Chem. 20/2024)

The Cover Feature demonstrates the crystal structure evolution of the [Cs(18‐crown‐6)][SbCl6] complex under high pressure. This unique structure offers valuable insights into the influence of pressure‐dependent interatomic interactions on the compression mechanism. Under pressure, the crystal exhibi...

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Veröffentlicht in:European journal of inorganic chemistry 2024-07, Vol.27 (20), p.n/a
Hauptverfasser: Rusanov, Eduard B., Wörle, Michael D., Kovalenko, Maksym V., Domasevitch, Kostiantyn V., Rusanova, Julia A.
Format: Artikel
Sprache:eng
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Zusammenfassung:The Cover Feature demonstrates the crystal structure evolution of the [Cs(18‐crown‐6)][SbCl6] complex under high pressure. This unique structure offers valuable insights into the influence of pressure‐dependent interatomic interactions on the compression mechanism. Under pressure, the crystal exhibits strong anisotropic behavior, the main compression occurring along cation–anion chains. This causes the Cs cations to gradually approach the center of the crown ether cavity, ultimately requiring 3 GPa for its complete encapsulation. More information can be found in the Research Article by E. B. Rusanov and co‐workers.
ISSN:1434-1948
1099-0682
DOI:10.1002/ejic.202482002