Novel Narrow Band Cyan‐Green Phosphor LiK 7 [Li 3 SiO 4 ] 8 :Eu 2+ with Enhanced Suppression of Second Broad Band Emission
LiK 7 [Li 3 SiO 4 ] 8 :Eu 2+ (LKLSO:Eu 2+ ) was synthesized by a high‐temperature solid‐state reaction. It is accessible from K 2 CO 3 , Li 2 O, SiO 2 , and an Eu‐source (Eu 2 O 3 ) by conventional solid‐state reaction in nickel crucibles under a constant flow of forming gas. The crystal structure o...
Gespeichert in:
| Veröffentlicht in: | European journal of inorganic chemistry 2021-11, Vol.2021 (43), p.4470-4481 |
|---|---|
| Hauptverfasser: | , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 4481 |
|---|---|
| container_issue | 43 |
| container_start_page | 4470 |
| container_title | European journal of inorganic chemistry |
| container_volume | 2021 |
| creator | Wimmer, Daniel S. Seibald, Markus Baumann, Dominik Peschke, Simon Wurst, Klaus Heymann, Gunter Dutzler, Daniel Garcia‐Fuente, Amador Urland, Werner Huppertz, Hubert |
| description | LiK
7
[Li
3
SiO
4
]
8
:Eu
2+
(LKLSO:Eu
2+
) was synthesized by a high‐temperature solid‐state reaction. It is accessible from K
2
CO
3
, Li
2
O, SiO
2
, and an Eu‐source (Eu
2
O
3
) by conventional solid‐state reaction in nickel crucibles under a constant flow of forming gas. The crystal structure of LKLSO has been determined by single‐crystal X‐ray diffraction and it crystallizes in the tetragonal space group
I
(no. 88) with the lattice parameters
a
=1560.83(5),
c
=1278.23(4) pm, and a volume of
V
=0.31140(2) nm
3
. The compound is isostructural to NaK
7
[Li
3
SiO
4
]
8
:Eu
2+
but, in contrast, features an enhanced suppression of the second broad band emission through the specific channel filling in the crystal structure. Despite the observed positional disorder in the structure, the cyan‐green phosphor shows a narrow band emission with a maximum at 511 nm and a fwhm of 45 nm (0.215 eV). |
| doi_str_mv | 10.1002/ejic.202100550 |
| format | Article |
| fullrecord | <record><control><sourceid>crossref</sourceid><recordid>TN_cdi_crossref_primary_10_1002_ejic_202100550</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1002_ejic_202100550</sourcerecordid><originalsourceid>FETCH-LOGICAL-c840-d7356a8d1688cfc8981a5fd224846e30ecb1c797432c9f3133ea991dcd9686f63</originalsourceid><addsrcrecordid>eNo9kM1KAzEcxIMoWKtXz_-7bM3XZhNvtqxVXFqhvYksMcmyKe1myVpLwYOP4DP6JLZWPM0MAzPwQ-iS4AHBmF67hTcDiukupCk-Qj2ClUqwkPR45znjCVFcnqKzrltgjBlmooc-JuHdLWGiYwwbGOrGwmirm-_Pr3F0roGnOnRtHSIU_hEyeC48MJj5KXB4AQk3-RroFWz8Ww15U-vGOAuzddtG13U-NBAqmDkTdrPDGLQ9POQr_9ueo5NKLzt38ad9NL_L56P7pJiOH0a3RWIkx4nNWCq0tERIaSojlSQ6rSylXHLhGHbmlZhMZZxRoypGGHNaKWKNVUKKSrA-GhxmTQxdF11VttGvdNyWBJd7dOUeXfmPjv0ALtNgRw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Novel Narrow Band Cyan‐Green Phosphor LiK 7 [Li 3 SiO 4 ] 8 :Eu 2+ with Enhanced Suppression of Second Broad Band Emission</title><source>Wiley Online Library - AutoHoldings Journals</source><creator>Wimmer, Daniel S. ; Seibald, Markus ; Baumann, Dominik ; Peschke, Simon ; Wurst, Klaus ; Heymann, Gunter ; Dutzler, Daniel ; Garcia‐Fuente, Amador ; Urland, Werner ; Huppertz, Hubert</creator><creatorcontrib>Wimmer, Daniel S. ; Seibald, Markus ; Baumann, Dominik ; Peschke, Simon ; Wurst, Klaus ; Heymann, Gunter ; Dutzler, Daniel ; Garcia‐Fuente, Amador ; Urland, Werner ; Huppertz, Hubert</creatorcontrib><description>LiK
7
[Li
3
SiO
4
]
8
:Eu
2+
(LKLSO:Eu
2+
) was synthesized by a high‐temperature solid‐state reaction. It is accessible from K
2
CO
3
, Li
2
O, SiO
2
, and an Eu‐source (Eu
2
O
3
) by conventional solid‐state reaction in nickel crucibles under a constant flow of forming gas. The crystal structure of LKLSO has been determined by single‐crystal X‐ray diffraction and it crystallizes in the tetragonal space group
I
(no. 88) with the lattice parameters
a
=1560.83(5),
c
=1278.23(4) pm, and a volume of
V
=0.31140(2) nm
3
. The compound is isostructural to NaK
7
[Li
3
SiO
4
]
8
:Eu
2+
but, in contrast, features an enhanced suppression of the second broad band emission through the specific channel filling in the crystal structure. Despite the observed positional disorder in the structure, the cyan‐green phosphor shows a narrow band emission with a maximum at 511 nm and a fwhm of 45 nm (0.215 eV).</description><identifier>ISSN: 1434-1948</identifier><identifier>EISSN: 1099-0682</identifier><identifier>DOI: 10.1002/ejic.202100550</identifier><language>eng</language><ispartof>European journal of inorganic chemistry, 2021-11, Vol.2021 (43), p.4470-4481</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c840-d7356a8d1688cfc8981a5fd224846e30ecb1c797432c9f3133ea991dcd9686f63</citedby><cites>FETCH-LOGICAL-c840-d7356a8d1688cfc8981a5fd224846e30ecb1c797432c9f3133ea991dcd9686f63</cites><orcidid>0000-0002-2098-6087</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27922,27923</link.rule.ids></links><search><creatorcontrib>Wimmer, Daniel S.</creatorcontrib><creatorcontrib>Seibald, Markus</creatorcontrib><creatorcontrib>Baumann, Dominik</creatorcontrib><creatorcontrib>Peschke, Simon</creatorcontrib><creatorcontrib>Wurst, Klaus</creatorcontrib><creatorcontrib>Heymann, Gunter</creatorcontrib><creatorcontrib>Dutzler, Daniel</creatorcontrib><creatorcontrib>Garcia‐Fuente, Amador</creatorcontrib><creatorcontrib>Urland, Werner</creatorcontrib><creatorcontrib>Huppertz, Hubert</creatorcontrib><title>Novel Narrow Band Cyan‐Green Phosphor LiK 7 [Li 3 SiO 4 ] 8 :Eu 2+ with Enhanced Suppression of Second Broad Band Emission</title><title>European journal of inorganic chemistry</title><description>LiK
7
[Li
3
SiO
4
]
8
:Eu
2+
(LKLSO:Eu
2+
) was synthesized by a high‐temperature solid‐state reaction. It is accessible from K
2
CO
3
, Li
2
O, SiO
2
, and an Eu‐source (Eu
2
O
3
) by conventional solid‐state reaction in nickel crucibles under a constant flow of forming gas. The crystal structure of LKLSO has been determined by single‐crystal X‐ray diffraction and it crystallizes in the tetragonal space group
I
(no. 88) with the lattice parameters
a
=1560.83(5),
c
=1278.23(4) pm, and a volume of
V
=0.31140(2) nm
3
. The compound is isostructural to NaK
7
[Li
3
SiO
4
]
8
:Eu
2+
but, in contrast, features an enhanced suppression of the second broad band emission through the specific channel filling in the crystal structure. Despite the observed positional disorder in the structure, the cyan‐green phosphor shows a narrow band emission with a maximum at 511 nm and a fwhm of 45 nm (0.215 eV).</description><issn>1434-1948</issn><issn>1099-0682</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNo9kM1KAzEcxIMoWKtXz_-7bM3XZhNvtqxVXFqhvYksMcmyKe1myVpLwYOP4DP6JLZWPM0MAzPwQ-iS4AHBmF67hTcDiukupCk-Qj2ClUqwkPR45znjCVFcnqKzrltgjBlmooc-JuHdLWGiYwwbGOrGwmirm-_Pr3F0roGnOnRtHSIU_hEyeC48MJj5KXB4AQk3-RroFWz8Ww15U-vGOAuzddtG13U-NBAqmDkTdrPDGLQ9POQr_9ueo5NKLzt38ad9NL_L56P7pJiOH0a3RWIkx4nNWCq0tERIaSojlSQ6rSylXHLhGHbmlZhMZZxRoypGGHNaKWKNVUKKSrA-GhxmTQxdF11VttGvdNyWBJd7dOUeXfmPjv0ALtNgRw</recordid><startdate>20211122</startdate><enddate>20211122</enddate><creator>Wimmer, Daniel S.</creator><creator>Seibald, Markus</creator><creator>Baumann, Dominik</creator><creator>Peschke, Simon</creator><creator>Wurst, Klaus</creator><creator>Heymann, Gunter</creator><creator>Dutzler, Daniel</creator><creator>Garcia‐Fuente, Amador</creator><creator>Urland, Werner</creator><creator>Huppertz, Hubert</creator><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-2098-6087</orcidid></search><sort><creationdate>20211122</creationdate><title>Novel Narrow Band Cyan‐Green Phosphor LiK 7 [Li 3 SiO 4 ] 8 :Eu 2+ with Enhanced Suppression of Second Broad Band Emission</title><author>Wimmer, Daniel S. ; Seibald, Markus ; Baumann, Dominik ; Peschke, Simon ; Wurst, Klaus ; Heymann, Gunter ; Dutzler, Daniel ; Garcia‐Fuente, Amador ; Urland, Werner ; Huppertz, Hubert</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c840-d7356a8d1688cfc8981a5fd224846e30ecb1c797432c9f3133ea991dcd9686f63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wimmer, Daniel S.</creatorcontrib><creatorcontrib>Seibald, Markus</creatorcontrib><creatorcontrib>Baumann, Dominik</creatorcontrib><creatorcontrib>Peschke, Simon</creatorcontrib><creatorcontrib>Wurst, Klaus</creatorcontrib><creatorcontrib>Heymann, Gunter</creatorcontrib><creatorcontrib>Dutzler, Daniel</creatorcontrib><creatorcontrib>Garcia‐Fuente, Amador</creatorcontrib><creatorcontrib>Urland, Werner</creatorcontrib><creatorcontrib>Huppertz, Hubert</creatorcontrib><collection>CrossRef</collection><jtitle>European journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wimmer, Daniel S.</au><au>Seibald, Markus</au><au>Baumann, Dominik</au><au>Peschke, Simon</au><au>Wurst, Klaus</au><au>Heymann, Gunter</au><au>Dutzler, Daniel</au><au>Garcia‐Fuente, Amador</au><au>Urland, Werner</au><au>Huppertz, Hubert</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Novel Narrow Band Cyan‐Green Phosphor LiK 7 [Li 3 SiO 4 ] 8 :Eu 2+ with Enhanced Suppression of Second Broad Band Emission</atitle><jtitle>European journal of inorganic chemistry</jtitle><date>2021-11-22</date><risdate>2021</risdate><volume>2021</volume><issue>43</issue><spage>4470</spage><epage>4481</epage><pages>4470-4481</pages><issn>1434-1948</issn><eissn>1099-0682</eissn><abstract>LiK
7
[Li
3
SiO
4
]
8
:Eu
2+
(LKLSO:Eu
2+
) was synthesized by a high‐temperature solid‐state reaction. It is accessible from K
2
CO
3
, Li
2
O, SiO
2
, and an Eu‐source (Eu
2
O
3
) by conventional solid‐state reaction in nickel crucibles under a constant flow of forming gas. The crystal structure of LKLSO has been determined by single‐crystal X‐ray diffraction and it crystallizes in the tetragonal space group
I
(no. 88) with the lattice parameters
a
=1560.83(5),
c
=1278.23(4) pm, and a volume of
V
=0.31140(2) nm
3
. The compound is isostructural to NaK
7
[Li
3
SiO
4
]
8
:Eu
2+
but, in contrast, features an enhanced suppression of the second broad band emission through the specific channel filling in the crystal structure. Despite the observed positional disorder in the structure, the cyan‐green phosphor shows a narrow band emission with a maximum at 511 nm and a fwhm of 45 nm (0.215 eV).</abstract><doi>10.1002/ejic.202100550</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0002-2098-6087</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1434-1948 |
| ispartof | European journal of inorganic chemistry, 2021-11, Vol.2021 (43), p.4470-4481 |
| issn | 1434-1948 1099-0682 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_ejic_202100550 |
| source | Wiley Online Library - AutoHoldings Journals |
| title | Novel Narrow Band Cyan‐Green Phosphor LiK 7 [Li 3 SiO 4 ] 8 :Eu 2+ with Enhanced Suppression of Second Broad Band Emission |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-14T06%3A35%3A16IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Novel%20Narrow%20Band%20Cyan%E2%80%90Green%20Phosphor%20LiK%207%20%5BLi%203%20SiO%204%20%5D%208%20:Eu%202+%20with%20Enhanced%20Suppression%20of%20Second%20Broad%20Band%20Emission&rft.jtitle=European%20journal%20of%20inorganic%20chemistry&rft.au=Wimmer,%20Daniel%20S.&rft.date=2021-11-22&rft.volume=2021&rft.issue=43&rft.spage=4470&rft.epage=4481&rft.pages=4470-4481&rft.issn=1434-1948&rft.eissn=1099-0682&rft_id=info:doi/10.1002/ejic.202100550&rft_dat=%3Ccrossref%3E10_1002_ejic_202100550%3C/crossref%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |