Structure and Properties of the Non‐Centrosymmetric Manganese(II) Borate Mn 5 (BO 3 ) 3 OH
The rose‐colored compound Mn 5 (BO 3 ) 3 OH was synthesized under high‐pressure/high‐temperature conditions of 2.5 GPa and 973 K in a Walker‐type multianvil press. Single‐crystal X‐ray structure determination yielded the non‐centrosymmetric monoclinic space group Pm (no. 6) with the lattice paramete...
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| Veröffentlicht in: | European journal of inorganic chemistry 2019-09, Vol.2019 (34), p.3854-3862 |
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| container_title | European journal of inorganic chemistry |
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| creator | Falkowski, Viktoria Zeugner, Alexander Bayarjargal, Lkhamsuren Saxer, Andreas Ruck, Michael Huppertz, Hubert |
| description | The rose‐colored compound Mn
5
(BO
3
)
3
OH was synthesized under high‐pressure/high‐temperature conditions of 2.5 GPa and 973 K in a Walker‐type multianvil press. Single‐crystal X‐ray structure determination yielded the non‐centrosymmetric monoclinic space group
Pm
(no. 6) with the lattice parameters
a
= 329.71(1),
b
= 1384.92(5),
c
= 902.37(3) pm, and
β
= 107.92(1)°. The presence of the hydroxide group is ascertained by vibrational spectroscopy. Magnetization experiments in the range from 300 to 14 K revealed paramagnetic behavior with antiferromagnetic ordering below 14 K and an effective magnetic moment of 12.2 µ
B
per formula unit. The acentric nature of the material was verified by second harmonic generation measurements, yielding a considerably strong intensity (I
sample
/I
quartz
= 11.14). Additionally, thermal investigations showed a several‐step transformation to Mn
2
OBO
3
upon heating under air. |
| doi_str_mv | 10.1002/ejic.201900769 |
| format | Article |
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5
(BO
3
)
3
OH was synthesized under high‐pressure/high‐temperature conditions of 2.5 GPa and 973 K in a Walker‐type multianvil press. Single‐crystal X‐ray structure determination yielded the non‐centrosymmetric monoclinic space group
Pm
(no. 6) with the lattice parameters
a
= 329.71(1),
b
= 1384.92(5),
c
= 902.37(3) pm, and
β
= 107.92(1)°. The presence of the hydroxide group is ascertained by vibrational spectroscopy. Magnetization experiments in the range from 300 to 14 K revealed paramagnetic behavior with antiferromagnetic ordering below 14 K and an effective magnetic moment of 12.2 µ
B
per formula unit. The acentric nature of the material was verified by second harmonic generation measurements, yielding a considerably strong intensity (I
sample
/I
quartz
= 11.14). Additionally, thermal investigations showed a several‐step transformation to Mn
2
OBO
3
upon heating under air.</description><identifier>ISSN: 1434-1948</identifier><identifier>EISSN: 1099-0682</identifier><identifier>DOI: 10.1002/ejic.201900769</identifier><language>eng</language><ispartof>European journal of inorganic chemistry, 2019-09, Vol.2019 (34), p.3854-3862</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-crossref_primary_10_1002_ejic_2019007693</cites><orcidid>0000-0002-8570-7659 ; 0000-0002-2098-6087 ; 0000-0002-2391-6025</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Falkowski, Viktoria</creatorcontrib><creatorcontrib>Zeugner, Alexander</creatorcontrib><creatorcontrib>Bayarjargal, Lkhamsuren</creatorcontrib><creatorcontrib>Saxer, Andreas</creatorcontrib><creatorcontrib>Ruck, Michael</creatorcontrib><creatorcontrib>Huppertz, Hubert</creatorcontrib><title>Structure and Properties of the Non‐Centrosymmetric Manganese(II) Borate Mn 5 (BO 3 ) 3 OH</title><title>European journal of inorganic chemistry</title><description>The rose‐colored compound Mn
5
(BO
3
)
3
OH was synthesized under high‐pressure/high‐temperature conditions of 2.5 GPa and 973 K in a Walker‐type multianvil press. Single‐crystal X‐ray structure determination yielded the non‐centrosymmetric monoclinic space group
Pm
(no. 6) with the lattice parameters
a
= 329.71(1),
b
= 1384.92(5),
c
= 902.37(3) pm, and
β
= 107.92(1)°. The presence of the hydroxide group is ascertained by vibrational spectroscopy. Magnetization experiments in the range from 300 to 14 K revealed paramagnetic behavior with antiferromagnetic ordering below 14 K and an effective magnetic moment of 12.2 µ
B
per formula unit. The acentric nature of the material was verified by second harmonic generation measurements, yielding a considerably strong intensity (I
sample
/I
quartz
= 11.14). Additionally, thermal investigations showed a several‐step transformation to Mn
2
OBO
3
upon heating under air.</description><issn>1434-1948</issn><issn>1099-0682</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNqVj71uwjAUha0KpELL2vmOMCS9jtMUryAqGPiR6IhkWeGmDWpsdG0GNh6hz9gnaZCq7gxH5yzfkT4hniSmEjF7pkNdphlKjfha6DvRk6h1gsU467Q7V3kidT6-F_0QDoioUBU9sdtGPpXxxATW7WHD_kgcawrgK4ifBCvvfi7fU3KRfTg3DUWuS1ha92EdBRouFiOYeLaRYOngBYaTNSgYtVnPH0W3sl-BBn_9INK32ft0npTtV2CqzJHrxvLZSDRXB3N1MP8O6mbgF3MJTgQ</recordid><startdate>20190915</startdate><enddate>20190915</enddate><creator>Falkowski, Viktoria</creator><creator>Zeugner, Alexander</creator><creator>Bayarjargal, Lkhamsuren</creator><creator>Saxer, Andreas</creator><creator>Ruck, Michael</creator><creator>Huppertz, Hubert</creator><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-8570-7659</orcidid><orcidid>https://orcid.org/0000-0002-2098-6087</orcidid><orcidid>https://orcid.org/0000-0002-2391-6025</orcidid></search><sort><creationdate>20190915</creationdate><title>Structure and Properties of the Non‐Centrosymmetric Manganese(II) Borate Mn 5 (BO 3 ) 3 OH</title><author>Falkowski, Viktoria ; Zeugner, Alexander ; Bayarjargal, Lkhamsuren ; Saxer, Andreas ; Ruck, Michael ; Huppertz, Hubert</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-crossref_primary_10_1002_ejic_2019007693</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Falkowski, Viktoria</creatorcontrib><creatorcontrib>Zeugner, Alexander</creatorcontrib><creatorcontrib>Bayarjargal, Lkhamsuren</creatorcontrib><creatorcontrib>Saxer, Andreas</creatorcontrib><creatorcontrib>Ruck, Michael</creatorcontrib><creatorcontrib>Huppertz, Hubert</creatorcontrib><collection>CrossRef</collection><jtitle>European journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Falkowski, Viktoria</au><au>Zeugner, Alexander</au><au>Bayarjargal, Lkhamsuren</au><au>Saxer, Andreas</au><au>Ruck, Michael</au><au>Huppertz, Hubert</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structure and Properties of the Non‐Centrosymmetric Manganese(II) Borate Mn 5 (BO 3 ) 3 OH</atitle><jtitle>European journal of inorganic chemistry</jtitle><date>2019-09-15</date><risdate>2019</risdate><volume>2019</volume><issue>34</issue><spage>3854</spage><epage>3862</epage><pages>3854-3862</pages><issn>1434-1948</issn><eissn>1099-0682</eissn><abstract>The rose‐colored compound Mn
5
(BO
3
)
3
OH was synthesized under high‐pressure/high‐temperature conditions of 2.5 GPa and 973 K in a Walker‐type multianvil press. Single‐crystal X‐ray structure determination yielded the non‐centrosymmetric monoclinic space group
Pm
(no. 6) with the lattice parameters
a
= 329.71(1),
b
= 1384.92(5),
c
= 902.37(3) pm, and
β
= 107.92(1)°. The presence of the hydroxide group is ascertained by vibrational spectroscopy. Magnetization experiments in the range from 300 to 14 K revealed paramagnetic behavior with antiferromagnetic ordering below 14 K and an effective magnetic moment of 12.2 µ
B
per formula unit. The acentric nature of the material was verified by second harmonic generation measurements, yielding a considerably strong intensity (I
sample
/I
quartz
= 11.14). Additionally, thermal investigations showed a several‐step transformation to Mn
2
OBO
3
upon heating under air.</abstract><doi>10.1002/ejic.201900769</doi><orcidid>https://orcid.org/0000-0002-8570-7659</orcidid><orcidid>https://orcid.org/0000-0002-2098-6087</orcidid><orcidid>https://orcid.org/0000-0002-2391-6025</orcidid></addata></record> |
| fulltext | fulltext |
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| ispartof | European journal of inorganic chemistry, 2019-09, Vol.2019 (34), p.3854-3862 |
| issn | 1434-1948 1099-0682 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_ejic_201900769 |
| source | Wiley Online Library Journals Frontfile Complete |
| title | Structure and Properties of the Non‐Centrosymmetric Manganese(II) Borate Mn 5 (BO 3 ) 3 OH |
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