Cyclometalation of Phosphanes at Iridium(I): Interplay with Intramolecular Reductive Elimination Induced by the Strong π-Acceptor Ligands CO and NO

Reaction of [{Ir(μ‐Cl)(coe)2}2] (1; coe = cis‐cyclooctene) with 4 equiv. of PtBu2Ph in CH2Cl2 at ambient temperature resulted in oxidative addition of one phosphane ligand affording the known cyclometalated IrIII complex [IrCl(H)(PtBu2C6H4‐κ2P,C)(PtBu2Ph)] (2) in high yield. Compound 2 exhibits a co...

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Veröffentlicht in:	European journal of inorganic chemistry 2015-07, Vol.2015 (20), p.3323-3327
Hauptverfasser:	Böttcher, Hans-Christian, Junk, Merlin, Mayer, Peter, Beck, Wolfgang
Format:	Artikel
Sprache:	eng
Schlagworte:	Cyclometalation Iridium Oxidative addition Phosphane ligands Reductive elimination
Online-Zugang:	Volltext
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